ZnMn2(PO4)2·nH2O: An H2O-Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries

Chunhui Wang; Keyi Xian; Shuangshuang Zhao; Lishan Yang; Junjian Zhou; Yahui Yang; Xiangping Chen; Jiang Yin; Jun Wang; Haozhe Qin; Zhongliang Tian; Yanqing Lai; Zhongchang Wang; Bao Zhang; Haiyan Wang

doi:10.1021/acs.nanolett.4c01420

ZnMn₂(PO₄)₂·nH₂O: An H₂O-Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries

Chunhui Wang
, Keyi Xian
, Shuangshuang Zhao
, Lishan Yang^*
, Junjian Zhou
, Yahui Yang
, Xiangping Chen
, Jiang Yin
, Jun Wang^*
, Haozhe Qin
, Zhongliang Tian
, Yanqing Lai
, Zhongchang Wang
, Bao Zhang
, Haiyan Wang^*

^*此作品的通讯作者

Hunan Normal University
University of South China
International Iberian Nanotechnology Laboratory
Wuhan University
Central South University

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn₂(PO₄)₂·nH₂O (ZMP·nH₂O) was obtained by a hydration reaction from ZnMn₂(PO₄)₂ (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H₂O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH₂O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H₂O and O in PO₄^3-, which strengthens the structure stability of ZMP·nH₂O and lowers the conversion barrier from ZMP to ZMP·4H₂O during the Zn²⁺ uptake/removal process. Thereof, ZMP·nH₂O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g^-1 at 100 mA g^-1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH₂O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.

源语言	英语
页（从-至）	9816-9823
页数	8
期刊	Nano Letters
卷	24
期	32
DOI	https://doi.org/10.1021/acs.nanolett.4c01420
出版状态	已出版 - 14 8月 2024
已对外发布	是

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10.1021/acs.nanolett.4c01420

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@article{5348b2438b7a4de681e7531bd204783f,

title = "ZnMn2(PO4)2·nH2O: An H2O-Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries",

abstract = "Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO43-, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g-1 at 100 mA g-1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.",

keywords = "V-free and Mn-based materials, Zn-ion batteries, electrode-aging evolution, electrolyte composition regulation, zinc manganese phosphate hydrate",

author = "Chunhui Wang and Keyi Xian and Shuangshuang Zhao and Lishan Yang and Junjian Zhou and Yahui Yang and Xiangping Chen and Jiang Yin and Jun Wang and Haozhe Qin and Zhongliang Tian and Yanqing Lai and Zhongchang Wang and Bao Zhang and Haiyan Wang",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = aug,

day = "14",

doi = "10.1021/acs.nanolett.4c01420",

language = "英语",

volume = "24",

pages = "9816--9823",

journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "32",

}

TY - JOUR

T1 - ZnMn2(PO4)2·nH2O

T2 - An H2O-Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries

AU - Wang, Chunhui

AU - Xian, Keyi

AU - Zhao, Shuangshuang

AU - Yang, Lishan

AU - Zhou, Junjian

AU - Yang, Yahui

AU - Chen, Xiangping

AU - Yin, Jiang

AU - Wang, Jun

AU - Qin, Haozhe

AU - Tian, Zhongliang

AU - Lai, Yanqing

AU - Wang, Zhongchang

AU - Zhang, Bao

AU - Wang, Haiyan

PY - 2024/8/14

Y1 - 2024/8/14

N2 - Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO43-, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g-1 at 100 mA g-1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.

AB - Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO43-, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g-1 at 100 mA g-1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.

KW - V-free and Mn-based materials

KW - Zn-ion batteries

KW - electrode-aging evolution

KW - electrolyte composition regulation

KW - zinc manganese phosphate hydrate

UR - https://www.scopus.com/pages/publications/85200408311

U2 - 10.1021/acs.nanolett.4c01420

DO - 10.1021/acs.nanolett.4c01420

M3 - 文章

C2 - 39094116

AN - SCOPUS:85200408311

SN - 1530-6984

VL - 24

SP - 9816

EP - 9823

JO - Nano Letters

JF - Nano Letters

IS - 32

ER -

ZnMn2(PO4)2·nH2O: An H2O-Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries

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ZnMn₂(PO₄)₂·nH₂O: An H₂O-Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries