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The influence of HSO3- activity on electrochemical characteristics of copper

  • Qian Liu*
  • , Chaofang Dong
  • , Kui Xiao
  • , Xiaogang Li
  • *此作品的通讯作者
  • University of Science and Technology Beijing
  • Beijing Key Laboratory for Network Technology

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

The electrochemical behavior of copper in various concentrations of NaHSO3 solution was investigated with linear polarization and cyclic voltametry technique at room temperature. The results showed that the concentration of bisulfite ions has noticeable effects on the behavior of copper. With HSO3-concentration increasing, the passivity region, ascribed to the formation of absorption layer Cu (HSO3) ads- or Cu (SO4) ads2-, appearing at the lower potential range in the polarization curve inclined to transform into an active region; whereas another passivity region, due to the appearance of CuO or Cu2O layer on the surface, took place at a higher potential region. The formation and the reduction of CuO or Cu 2O were irreversible.

源语言英语
主期刊名Advances in Superalloys
654-660
页数7
DOI
出版状态已出版 - 2011
已对外发布
活动2010 International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2010 - Shenzhen, 中国
期限: 6 11月 20108 11月 2010

出版系列

姓名Advanced Materials Research
146-147
ISSN(印刷版)1022-6680

会议

会议2010 International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2010
国家/地区中国
Shenzhen
时期6/11/108/11/10

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