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The ideal glass transition of hard spheres

科研成果: 期刊稿件文章同行评审

摘要

We use the replica method to study the ideal glass transition of a liquid of identical hard spheres. We obtain estimates of the configurational entropy in the liquid phase, of the Kauzmann packing fraction φ K, in the range of 0.58-0.62, and of the random close packing density φ c, in the range of 0.64-0.67, depending on the approximation we use for the equation of state of the liquid. We also compute the pair-correlation function in the glassy states (i.e., dense amorphous packings) and we find that the mean coordination number at φ c is equal to 6. All these results compare well with numerical simulations and with other existing theories.

源语言英语
文章编号144501
期刊Journal of Chemical Physics
123
14
DOI
出版状态已出版 - 8 10月 2005
已对外发布

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