摘要
We use the replica method to study the ideal glass transition of a liquid of identical hard spheres. We obtain estimates of the configurational entropy in the liquid phase, of the Kauzmann packing fraction φ K, in the range of 0.58-0.62, and of the random close packing density φ c, in the range of 0.64-0.67, depending on the approximation we use for the equation of state of the liquid. We also compute the pair-correlation function in the glassy states (i.e., dense amorphous packings) and we find that the mean coordination number at φ c is equal to 6. All these results compare well with numerical simulations and with other existing theories.
| 源语言 | 英语 |
|---|---|
| 文章编号 | 144501 |
| 期刊 | Journal of Chemical Physics |
| 卷 | 123 |
| 期 | 14 |
| DOI | |
| 出版状态 | 已出版 - 8 10月 2005 |
| 已对外发布 | 是 |
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