TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

Teng Wang; Ning Jiao

doi:10.1021/ja403824y

TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

Teng Wang
, Ning Jiao^*

^*此作品的通讯作者

Peking University
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

238 引用（Scopus）

摘要

A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

源语言	英语
页（从-至）	11692-11695
页数	4
期刊	Journal of the American Chemical Society
卷	135
期	32
DOI	https://doi.org/10.1021/ja403824y
出版状态	已出版 - 14 8月 2013
已对外发布	是

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10.1021/ja403824y

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abstract = "A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.",

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AU - Wang, Teng

AU - Jiao, Ning

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N2 - A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

AB - A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

UR - https://www.scopus.com/pages/publications/84882276526

U2 - 10.1021/ja403824y

DO - 10.1021/ja403824y

M3 - 文章

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AN - SCOPUS:84882276526

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JF - Journal of the American Chemical Society

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TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

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