Synthesis, characterization and photostability of several soluble tetra(quinolin-8-yloxy)metallophthalocyanines

Fangdi Cong; Dongliang Tian; Junshan Gao; Wenjuan Duan; Chunyu Ma; Xiguang Du

doi:10.1016/j.ica.2007.07.007

Synthesis, characterization and photostability of several soluble tetra(quinolin-8-yloxy)metallophthalocyanines

Fangdi Cong
, Dongliang Tian
, Junshan Gao
, Wenjuan Duan
, Chunyu Ma
, Xiguang Du^*

^*此作品的通讯作者

Nanjing University of Aeronautics and Astronautics
Northeast Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

Five tetra(quinolin-8-yloxy)metallophthalocyanines 4a-4e were synthesized from 4-(quinolin-8-yloxy)phthalonitrile in the presence of 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) as the catalyst, and characterized by MS, ¹H NMR, UV-Vis, IR and elemental analysis, which were consistent with the proposed structures. The Q band wavelength of them is related to the metal species in center of Pc rings and follows an order: Mn > Zn ≈ Cu > Ni ≈ Co. They all possess excellent solubility in several polar organic solvents, such as chloroform and dichloromethane. But the stability of them, especially that with zinc as coordinated center, is very poor in solutions.

源语言	英语
页（从-至）	243-246
页数	4
期刊	Inorganica Chimica Acta
卷	362
期	1
DOI	https://doi.org/10.1016/j.ica.2007.07.007
出版状态	已出版 - 1 1月 2009
已对外发布	是

访问文件

10.1016/j.ica.2007.07.007

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{52a3e3006733482ca6a2e87c5c5bd1ac,

title = "Synthesis, characterization and photostability of several soluble tetra(quinolin-8-yloxy)metallophthalocyanines",

abstract = "Five tetra(quinolin-8-yloxy)metallophthalocyanines 4a-4e were synthesized from 4-(quinolin-8-yloxy)phthalonitrile in the presence of 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) as the catalyst, and characterized by MS, 1H NMR, UV-Vis, IR and elemental analysis, which were consistent with the proposed structures. The Q band wavelength of them is related to the metal species in center of Pc rings and follows an order: Mn > Zn ≈ Cu > Ni ≈ Co. They all possess excellent solubility in several polar organic solvents, such as chloroform and dichloromethane. But the stability of them, especially that with zinc as coordinated center, is very poor in solutions.",

keywords = "Characterization, Photostability, Phthalocyanine, Solubility, Synthesis",

author = "Fangdi Cong and Dongliang Tian and Junshan Gao and Wenjuan Duan and Chunyu Ma and Xiguang Du",

year = "2009",

month = jan,

day = "1",

doi = "10.1016/j.ica.2007.07.007",

language = "英语",

volume = "362",

pages = "243--246",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Synthesis, characterization and photostability of several soluble tetra(quinolin-8-yloxy)metallophthalocyanines

AU - Cong, Fangdi

AU - Tian, Dongliang

AU - Gao, Junshan

AU - Duan, Wenjuan

AU - Ma, Chunyu

AU - Du, Xiguang

PY - 2009/1/1

Y1 - 2009/1/1

N2 - Five tetra(quinolin-8-yloxy)metallophthalocyanines 4a-4e were synthesized from 4-(quinolin-8-yloxy)phthalonitrile in the presence of 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) as the catalyst, and characterized by MS, 1H NMR, UV-Vis, IR and elemental analysis, which were consistent with the proposed structures. The Q band wavelength of them is related to the metal species in center of Pc rings and follows an order: Mn > Zn ≈ Cu > Ni ≈ Co. They all possess excellent solubility in several polar organic solvents, such as chloroform and dichloromethane. But the stability of them, especially that with zinc as coordinated center, is very poor in solutions.

AB - Five tetra(quinolin-8-yloxy)metallophthalocyanines 4a-4e were synthesized from 4-(quinolin-8-yloxy)phthalonitrile in the presence of 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) as the catalyst, and characterized by MS, 1H NMR, UV-Vis, IR and elemental analysis, which were consistent with the proposed structures. The Q band wavelength of them is related to the metal species in center of Pc rings and follows an order: Mn > Zn ≈ Cu > Ni ≈ Co. They all possess excellent solubility in several polar organic solvents, such as chloroform and dichloromethane. But the stability of them, especially that with zinc as coordinated center, is very poor in solutions.

KW - Characterization

KW - Photostability

KW - Phthalocyanine

KW - Solubility

KW - Synthesis

UR - https://www.scopus.com/pages/publications/56649108099

U2 - 10.1016/j.ica.2007.07.007

DO - 10.1016/j.ica.2007.07.007

M3 - 文章

AN - SCOPUS:56649108099

SN - 0020-1693

VL - 362

SP - 243

EP - 246

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Synthesis, characterization and photostability of several soluble tetra(quinolin-8-yloxy)metallophthalocyanines

摘要

访问文件

其它文件与链接

指纹

引用此