Synthesis and structure of the first three-leg ladder of coordination polymer: {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n

B. Sun; Z. Wang; S. Gao

Synthesis and structure of the first three-leg ladder of coordination polymer: {Zn₃(Ac)₄(4,4′-bpy)₃ [N(CN)₂]₂}_n

B. Sun^*
, Z. Wang
, S. Gao

^*此作品的通讯作者

Peking University

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The coordination polymer {Zn₃(Ac)₄(4,4′-bpy)₃ [N(CN)₂]₂}_n is prepared and characterized by X-ray diffraction. It is an unique three-leg molecular ladder. Crystal data: {Zn₃(Ac)₄(4,4′-bpy)₃ [N(CN)₂]₂}_n, monoclinic, space group C2/c, a = 21.603 4(13), b = 11.456 6(7), c = 17.798 2(12)Å, β = 104.245(4)°, V = 4 269.6(5)Å³, Z = 4, D_c = 1.607 Mg/m³, μ = 1.741cm^-1, R1 = 0.050 6 and wR2 = 0.087 7.Zn(II) atoms are located at the crosspoint of the "rungs" and "rails". Each Zn^II atom located at the side rails has a trigonal bipyramid environment. The Zn^II(2) atom located at the crosspoint of the ladder displays octahedral coordination.

源语言	英语
页（从-至）	271-272
页数	2
期刊	Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis
卷	37
期	2
出版状态	已出版 - 3月 2001
已对外发布	是

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{0673dc73bff54c8eb08bd5e43af80369,

title = "Synthesis and structure of the first three-leg ladder of coordination polymer: \{Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2\}n",

abstract = "The coordination polymer \{Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2\}n is prepared and characterized by X-ray diffraction. It is an unique three-leg molecular ladder. Crystal data: \{Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2\}n, monoclinic, space group C2/c, a = 21.603 4(13), b = 11.456 6(7), c = 17.798 2(12){\AA}, β = 104.245(4)°, V = 4 269.6(5){\AA}3, Z = 4, Dc = 1.607 Mg/m3, μ = 1.741cm-1, R1 = 0.050 6 and wR2 = 0.087 7.Zn(II) atoms are located at the crosspoint of the {"}rungs{"} and {"}rails{"}. Each ZnII atom located at the side rails has a trigonal bipyramid environment. The ZnII(2) atom located at the crosspoint of the ladder displays octahedral coordination.",

keywords = "Coordination polymer, Crystal, Ladder-like structure",

author = "B. Sun and Z. Wang and S. Gao",

year = "2001",

month = mar,

language = "英语",

volume = "37",

pages = "271--272",

journal = "Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis",

issn = "0479-8023",

publisher = "Peking University",

number = "2",

}

TY - JOUR

T1 - Synthesis and structure of the first three-leg ladder of coordination polymer

T2 - {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n

AU - Sun, B.

AU - Wang, Z.

AU - Gao, S.

PY - 2001/3

Y1 - 2001/3

N2 - The coordination polymer {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n is prepared and characterized by X-ray diffraction. It is an unique three-leg molecular ladder. Crystal data: {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n, monoclinic, space group C2/c, a = 21.603 4(13), b = 11.456 6(7), c = 17.798 2(12)Å, β = 104.245(4)°, V = 4 269.6(5)Å3, Z = 4, Dc = 1.607 Mg/m3, μ = 1.741cm-1, R1 = 0.050 6 and wR2 = 0.087 7.Zn(II) atoms are located at the crosspoint of the "rungs" and "rails". Each ZnII atom located at the side rails has a trigonal bipyramid environment. The ZnII(2) atom located at the crosspoint of the ladder displays octahedral coordination.

AB - The coordination polymer {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n is prepared and characterized by X-ray diffraction. It is an unique three-leg molecular ladder. Crystal data: {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n, monoclinic, space group C2/c, a = 21.603 4(13), b = 11.456 6(7), c = 17.798 2(12)Å, β = 104.245(4)°, V = 4 269.6(5)Å3, Z = 4, Dc = 1.607 Mg/m3, μ = 1.741cm-1, R1 = 0.050 6 and wR2 = 0.087 7.Zn(II) atoms are located at the crosspoint of the "rungs" and "rails". Each ZnII atom located at the side rails has a trigonal bipyramid environment. The ZnII(2) atom located at the crosspoint of the ladder displays octahedral coordination.

KW - Coordination polymer

KW - Crystal

KW - Ladder-like structure

UR - https://www.scopus.com/pages/publications/0035279077

M3 - 文章

AN - SCOPUS:0035279077

SN - 0479-8023

VL - 37

SP - 271

EP - 272

JO - Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis

JF - Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis

IS - 2

ER -

Synthesis and structure of the first three-leg ladder of coordination polymer: {Zn3(Ac)4(4,4′-bpy)3 [N(CN)2]2}n

摘要

其它文件与链接

指纹

引用此

Synthesis and structure of the first three-leg ladder of coordination polymer: {Zn₃(Ac)₄(4,4′-bpy)₃ [N(CN)₂]₂}_n