Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Tao Shen; Teng Wang; Chong Qin; Ning Jiao

doi:10.1002/anie.201300193

Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Tao Shen
, Teng Wang
, Chong Qin
, Ning Jiao^*

^*此作品的通讯作者

Peking University
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

170 引用（Scopus）

摘要

Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.

源语言	英语
页（从-至）	6677-6680
页数	4
期刊	Angewandte Chemie - International Edition
卷	52
期	26
DOI	https://doi.org/10.1002/anie.201300193
出版状态	已出版 - 24 6月 2013
已对外发布	是

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10.1002/anie.201300193

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abstract = "Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.",

keywords = "alkynes, azides, nitriles, rearrangement, silver",

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T2 - A direct approach to nitriles through C≡C bond cleavage

AU - Shen, Tao

AU - Wang, Teng

AU - Qin, Chong

AU - Jiao, Ning

PY - 2013/6/24

Y1 - 2013/6/24

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AB - Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.

KW - alkynes

KW - azides

KW - nitriles

KW - rearrangement

KW - silver

UR - https://www.scopus.com/pages/publications/84879351373

U2 - 10.1002/anie.201300193

DO - 10.1002/anie.201300193

M3 - 文章

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AN - SCOPUS:84879351373

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

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