Selective Csp2-Csp bond cleavage: The nitrogenation of alkynes to amides

Chong Qin; Peng Feng; Yang Ou; Tao Shen; Teng Wang; Ning Jiao

doi:10.1002/anie.201303376

Selective C_sp²-C_sp bond cleavage: The nitrogenation of alkynes to amides

Chong Qin
, Peng Feng
, Yang Ou
, Tao Shen
, Teng Wang
, Ning Jiao^*

^*此作品的通讯作者

Peking University
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

90 引用（Scopus）

摘要

Breakthrough: A novel catalyzed direct highly selective C sp 2-C _sp bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2-C_sp bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.

源语言	英语
页（从-至）	7850-7854
页数	5
期刊	Angewandte Chemie - International Edition
卷	52
期	30
DOI	https://doi.org/10.1002/anie.201303376
出版状态	已出版 - 22 7月 2013
已对外发布	是

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title = "Selective Csp2-Csp bond cleavage: The nitrogenation of alkynes to amides",

abstract = "Breakthrough: A novel catalyzed direct highly selective C sp 2-C sp bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2-Csp bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.",

keywords = "C-C bond cleavage, alkynes, amides, gold, rearrangement",

author = "Chong Qin and Peng Feng and Yang Ou and Tao Shen and Teng Wang and Ning Jiao",

year = "2013",

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T2 - The nitrogenation of alkynes to amides

AU - Qin, Chong

AU - Feng, Peng

AU - Ou, Yang

AU - Shen, Tao

AU - Wang, Teng

AU - Jiao, Ning

PY - 2013/7/22

Y1 - 2013/7/22

N2 - Breakthrough: A novel catalyzed direct highly selective C sp 2-C sp bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2-Csp bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.

AB - Breakthrough: A novel catalyzed direct highly selective C sp 2-C sp bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2-Csp bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.

KW - C-C bond cleavage

KW - alkynes

KW - amides

KW - gold

KW - rearrangement

UR - https://www.scopus.com/pages/publications/84880395260

U2 - 10.1002/anie.201303376

DO - 10.1002/anie.201303376

M3 - 文章

C2 - 23804537

AN - SCOPUS:84880395260

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JF - Angewandte Chemie - International Edition

IS - 30

ER -

Selective Csp2-Csp bond cleavage: The nitrogenation of alkynes to amides

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Selective C_sp²-C_sp bond cleavage: The nitrogenation of alkynes to amides