Quenching-Induced Defect-Rich Platinum/Metal Oxide Catalysts Promote Catalytic Oxidation

Enhancing oxygen activation through defect engineering is an effective strategy for boosting catalytic oxidation performance. Herein, we demonstrate that quenching is an effective strategy for preparing defect-rich Pt/metal oxide catalysts with superior catalytic oxidation activity. As a proof of concept, quenching of α-Fe₂O₃ in aqueous Pt(NO₃)₂ solution yielded a catalyst containing Pt single atoms and clusters over defect-rich α-Fe₂O₃ (Pt/Fe₂O₃-Q), which possessed state-of-the-art activity for toluene oxidation. Structural and spectroscopic analyses established that the quenching process created abundant lattice defects and lattice dislocations in the α-Fe₂O₃ support, and stronger electronic interactions between Pt species and Fe₂O₃ promote the generation of higher oxidation Pt species to modulate the adsorption/desorption behavior of reactants. In situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) characterization studies and density functional theory (DFT) calculations determined that molecular oxygen and Fe₂O₃ lattice oxygen were both activated on the Pt/Fe₂O₃-Q catalyst. Pt/CoMn₂O₄, Pt/MnO₂, and Pt/LaFeO₃ catalysts synthesized by the quenching method also offered superior catalytic activity for toluene oxidation. Results encourage the wider use of quenching for the preparation of highly active oxidation catalysts.