Preparation of geopolymer based on lunar regolith simulant at in-situ lunar temperature and its durability under lunar high and cryogenic temperature

Lunar base construction is of great importance for deep space exploration, and the establishment of lunar pavements for the movement of machinery and transportation of materials is essential to improve construction efficiency. Lunar regolith as an in-situ resource has been demonstrated to be used as raw materials to prepare geopolymers for lunar pavements. In this paper, geopolymers based on lunar regolith simulant with different concentrations of alkali activator were synthesized using the natural high-temperature of the lunar surface. Then, the durability of the resulting geopolymer under lunar high and cryogenic temperature was investigated. The flexural and compressive strength was tested, and the microstructure was characterized using Scanning Electron Microscope coupled with Energy Dispersive Spectroscopy (SEM-EDS), ²⁹Si Magic Angle Spinning-Nuclear Magnetic Resonance (²⁹Si MAS-NMR), and Mercury Intrusion Porosimetry (MIP). The results of the curing section showed that the geopolymer with 8 mol/L sodium hydroxide (NaOH) generated high strength and dense structure, and the period of 420 h–492 h of a lunar day corresponding to a temperature variation from 84.5 °C to 33.5 °C in 72 h was suitable for preparation, with 5.7 MPa and 31.2 MPa 72-h flexural and compressive strength. Three test points were selected on the lunar 30° latitude temperature curve, corresponding to before and after the cryogenic attack, and after high temperature again to investigate the durability of the geopolymer, and the degradation was found noticeable. The flexural strength decreased about 49% and 70%, and the compressive strength decreased about 15% and 18% after the cryogenic temperature and high temperature again, respectively. Microscopic observations revealed that the geopolymer structure was significantly granulated with obvious cracks and increased porosity. In addition, the formation of the zeolitic phase was unexpectedly found, leading to interfacial cracks and mechanical strength reduction of the geopolymer. This paper will be beneficial to explore the evolution of properties of lunar pavement construction materials in the lunar environment.