Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries

Weihua Pu; Shichao Zhang; Lan Zhang; Xiangming He; Chunrong Wan; Changyin Jiang

doi:10.1149/1.3123133

Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries

Weihua Pu^*
, Shichao Zhang
, Lan Zhang
, Xiangming He
, Chunrong Wan
, Changyin Jiang

^*此作品的通讯作者

材料科学与工程学院

Tsinghua University
Beihang University

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

2 引用（Scopus）

摘要

A novel acrylonitrile (AN)-based copolymer, P (acrylonitrile (AN) - methyl methacrylate (MMA)-methoxy polyethylene glycol (350) monoacrylate (MPGA)-lithium acrylate (LiAc)) (PAMMGLiAc) gel electrolytes were prepared in this paper. The physical properties of the AN-based copolymer membranes were characterized by IR, NMR, TGA, DSC and tensile test. The electrochemical characteristics of the AN-based gel electrolytes were investigated by electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV). The results show that the gel electrolytes have high ionic conductivity over 2×10^-3S/cm at room temperature, good mechanical properties and a sufficient electrochemical stability with a decomposition voltage as high as 6V vs. Li. The Li/gel electrolyte/LiFePO₄ coin cells with the prepared copolymer gel electrolytes also showed a good charge/discharge performance.

源语言	英语
主期刊名	ECS Transactions - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting
页	115-122
页数	8
版本	35
DOI	https://doi.org/10.1149/1.3123133
出版状态	已出版 - 2009
活动	Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting - Honolulu, HI, 美国期限: 12 10月 2008 → 17 10月 2008

出版系列

姓名	ECS Transactions
编号	35
卷	16
ISSN（印刷版）	1938-5862
ISSN（电子版）	1938-6737

会议

会议	Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting
国家/地区	美国
市	Honolulu, HI
时期	12/10/08 → 17/10/08

联合国可持续发展目标

此成果有助于实现下列可持续发展目标：

可持续发展目标 7 经济适用的清洁能源

访问文件

10.1149/1.3123133

其它文件与链接

链接到 Scopus 的出版物

引用此

Pu, W., Zhang, S., Zhang, L., He, X., Wan, C., & Jiang, C. (2009). Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries. 在 ECS Transactions - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting (35 编辑, 页码 115-122). (ECS Transactions; 卷 16, 号码 35). https://doi.org/10.1149/1.3123133

@inproceedings{8628bbe77ff641d9bfd1d0d86f00572b,

title = "Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries",

abstract = "A novel acrylonitrile (AN)-based copolymer, P (acrylonitrile (AN) - methyl methacrylate (MMA)-methoxy polyethylene glycol (350) monoacrylate (MPGA)-lithium acrylate (LiAc)) (PAMMGLiAc) gel electrolytes were prepared in this paper. The physical properties of the AN-based copolymer membranes were characterized by IR, NMR, TGA, DSC and tensile test. The electrochemical characteristics of the AN-based gel electrolytes were investigated by electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV). The results show that the gel electrolytes have high ionic conductivity over 2×10-3S/cm at room temperature, good mechanical properties and a sufficient electrochemical stability with a decomposition voltage as high as 6V vs. Li. The Li/gel electrolyte/LiFePO4 coin cells with the prepared copolymer gel electrolytes also showed a good charge/discharge performance.",

author = "Weihua Pu and Shichao Zhang and Lan Zhang and Xiangming He and Chunrong Wan and Changyin Jiang",

year = "2009",

doi = "10.1149/1.3123133",

language = "英语",

isbn = "9781615673087",

series = "ECS Transactions",

number = "35",

pages = "115--122",

booktitle = "ECS Transactions - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting",

edition = "35",

note = "Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting ; Conference date: 12-10-2008 Through 17-10-2008",

}

Pu, W, Zhang, S, Zhang, L, He, X, Wan, C & Jiang, C 2009, Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries. 在 ECS Transactions - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting. 35 编辑, ECS Transactions, 号码 35, 卷 16, 页码 115-122, Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting, Honolulu, HI, 美国, 12/10/08. https://doi.org/10.1149/1.3123133

Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries. / Pu, Weihua; Zhang, Shichao; Zhang, Lan 等.
ECS Transactions - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting. 35. 编辑 2009. 页码 115-122 (ECS Transactions; 卷 16, 号码 35).

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

TY - GEN

T1 - Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries

AU - Pu, Weihua

AU - Zhang, Shichao

AU - Zhang, Lan

AU - He, Xiangming

AU - Wan, Chunrong

AU - Jiang, Changyin

PY - 2009

Y1 - 2009

N2 - A novel acrylonitrile (AN)-based copolymer, P (acrylonitrile (AN) - methyl methacrylate (MMA)-methoxy polyethylene glycol (350) monoacrylate (MPGA)-lithium acrylate (LiAc)) (PAMMGLiAc) gel electrolytes were prepared in this paper. The physical properties of the AN-based copolymer membranes were characterized by IR, NMR, TGA, DSC and tensile test. The electrochemical characteristics of the AN-based gel electrolytes were investigated by electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV). The results show that the gel electrolytes have high ionic conductivity over 2×10-3S/cm at room temperature, good mechanical properties and a sufficient electrochemical stability with a decomposition voltage as high as 6V vs. Li. The Li/gel electrolyte/LiFePO4 coin cells with the prepared copolymer gel electrolytes also showed a good charge/discharge performance.

AB - A novel acrylonitrile (AN)-based copolymer, P (acrylonitrile (AN) - methyl methacrylate (MMA)-methoxy polyethylene glycol (350) monoacrylate (MPGA)-lithium acrylate (LiAc)) (PAMMGLiAc) gel electrolytes were prepared in this paper. The physical properties of the AN-based copolymer membranes were characterized by IR, NMR, TGA, DSC and tensile test. The electrochemical characteristics of the AN-based gel electrolytes were investigated by electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV). The results show that the gel electrolytes have high ionic conductivity over 2×10-3S/cm at room temperature, good mechanical properties and a sufficient electrochemical stability with a decomposition voltage as high as 6V vs. Li. The Li/gel electrolyte/LiFePO4 coin cells with the prepared copolymer gel electrolytes also showed a good charge/discharge performance.

UR - https://www.scopus.com/pages/publications/70449642876

U2 - 10.1149/1.3123133

DO - 10.1149/1.3123133

M3 - 会议稿件

AN - SCOPUS:70449642876

SN - 9781615673087

T3 - ECS Transactions

SP - 115

EP - 122

BT - ECS Transactions - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting

T2 - Non-Aqueous Electrolytes for Lithium Batteries - 214th ECS Meeting

Y2 - 12 October 2008 through 17 October 2008

ER -

Preparation and performance of novel acrylonitrile (AN)-based copolymer gel electrolytes for lithium ion batteries

摘要

出版系列

会议

联合国可持续发展目标

访问文件

其它文件与链接

指纹

引用此