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Preparation and characterization of a novel gel polymer membrane based on a tetra-copolymer

  • Beihang University

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

A acrylonitrile (AN)-methyl acrylate (MMA)-methoxy polyethylene glycol(350) monoacrylate (MPGA)-lithium acrylate (LiAc) tetra-copolymer was synthesized by emulsion polymerization, and phase inversion technique was adopted to prepare the as prepared polymer based microporous membrane. The gel polymer electrolytes (GPEs) were obtained by soak the as-prepared microporous membrane into 1M LiPF 6/ (EC (ethylene carbonate) + DEC (diethylene carbonate)) (1:1 vol) electrolyte. FTIR, NMR and TGA/DSC measurements are used to character the components and structure of the polymer. The GPE's ionic conductivity exceeds 3.0?0 -3S/cm at ambient temperature, and this system also shows a sufficient electrochemical stability with a decomposition voltage as much as 6.0V vs Lithium(Li)/Li+ to allow far wider operation in the rechargeable lithium-ion polymer batteries. What's more, this membrane also shows good characters in battery's charge-discharge cycles.

源语言英语
主期刊名Advances in Chemical Engineering
1755-1759
页数5
DOI
出版状态已出版 - 2012
活动2011 International Conference on Chemical, Material and Metallurgical Engineering, ICCMME 2011 - Beihai, 中国
期限: 23 12月 201125 12月 2011

出版系列

姓名Advanced Materials Research
396-398
ISSN(印刷版)1022-6680

会议

会议2011 International Conference on Chemical, Material and Metallurgical Engineering, ICCMME 2011
国家/地区中国
Beihai
时期23/12/1125/12/11

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