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Photoluminescence properties influenced by calcining condition and doping concentration of nano-sized ZnGa2O4: Cr3+

  • Weiwei Zhang*
  • , Junying Zhang
  • , Hui Wan
  • , Ziyu Chen
  • , Tianmin Wang
  • *此作品的通讯作者

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

Chromium-activated ZnGa2O4 nano-sized phosphor powder was prepared by the Sol-Gel technique using citric acid as chelator, and the microstructure and luminescent property were studied. The host ZnGa 2O4 belongs to the spinel structure and the ZnGa 2O4:Cr3+ phosphor powder exhibited bright red emission band. The excitation bands with peak of maximum height at about 250 nm, 410 nm and 560 nm were related to the charge transfer (CT) of Ga-O, 4 A2-4 T1 and 4 A 2-4 T2 transitions of Cr3+, respectively. Different quenching concentrations of the CT state and intrinsic excitation were discovered originating from different energy transfer schemes. Meanwhile, with the increasing of the calcining temperature the PLE spectrum exhibited an obvious blue-shift which is attributed to the enhancement of the crystal field.

源语言英语
主期刊名Materials Research
编辑Zhongwei Gu, Zhongwei Gu, Zhongwei Gu, Yafang Han, Yafang Han, Yafang Han, Fusheng Pan, Fusheng Pan, Fusheng Pan, Fusheng Pan, Fusheng Pan, Fusheng Pan, Xitao Wang, Xitao Wang, Xitao Wang, Duan Weng, Duan Weng, Duan Weng, Shaoxiong Zhou, Shaoxiong Zhou, Shaoxiong Zhou
出版商Trans Tech Publications Ltd
616-620
页数5
ISBN(印刷版)9780878493401, 9780878493401, 9780878493401
DOI
出版状态已出版 - 2009
活动MRS International Materials Research Conference, IMRC 2008 - Chongqing, 中国
期限: 9 6月 200812 6月 2008

出版系列

姓名Materials Science Forum
610-613
ISSN(印刷版)0255-5476
ISSN(电子版)1662-9752

会议

会议MRS International Materials Research Conference, IMRC 2008
国家/地区中国
Chongqing
时期9/06/0812/06/08

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