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Passivating the Surface of TiO2 Photoelectrodes with Nb2O5 and Al2O3 for High-Efficiency Dye-Sensitized Solar Cells

  • Beihang University

科研成果: 书/报告/会议事项章节章节同行评审

摘要

In this contribution, we reported a method to passivate the surface of the TiO2 photoelectrode with Nb2O5 and Al2O3 layer, and its application for the dye-sensitized solar cells. The surface of TiO2 photoelectrode was passivated by depositing Nb2O5 and Al2O3 layer in turn using surface sol–gel technology. After the TiO2 photoelectrode was passivated by Nb2O5 layer, the efficiency of the TiO2/Nb2O5 cell increased from 3.6 to 4.0 %. The Al2O3 layer on the TiO2/Nb2O5 electrode further suppressed the generation of the dark current, resulting in 25 % improvement in device performance comparing with that of the TiO2/Nb2O5 cell. The electrochemical impedance spectroscopy was used to investigate the influence of the Nb2O5 and Al2O3 layer on the Helmholtz layer capacitance of the TiO2 electrode, and provided the evidences for the formation of the energy barriers.

源语言英语
主期刊名Nanostructure Science and Technology
出版商Springer Publishing Company
201-210
页数10
DOI
出版状态已出版 - 2014

出版系列

姓名Nanostructure Science and Technology
174
ISSN(印刷版)1571-5744
ISSN(电子版)2197-7976

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