On-line cure monitoring of phenol formaldehyde resin using embedded fiber Bragg grating sensor

On-line cure monitoring techniques have shown advantages for identifying the stages of curing and can lead to smart curing process of resin system and its composites. In this study, an on-line measuring technique with fiber Bragg grating (FBG) sensors was used to gain clear understanding of the curing stages of phenolic resin, as well as to determine its chemical shrinkage level. The FBG sensors were embedded in phenolic resin and worked under temperature raising and isothermal conditions. Through the interface between FBG sensor and resin, curing shrinkage strain was transferred to the grating, changing the central wavelength of FBG and producing strain. The feasibility of FBG sensors for monitoring chemical shrinkage during curing was verified by employing epoxy and benzoxazine resins that exhibits low chemical shrinkage. For cure monitoring of phenolic resin, the results show that the strain signal can be corresponded to various responses, such as solvent volatilization, hydroxylation and dehydration condensation reactions during temperature raising curing process. Through these strain characteristics, the curing state of phenolic resin can be obtained, which degree of cure ranges from 0.05 to 0.9. In isothermal curing process of phenolic resin, an exponential correlation between chemical shrinkage induced compressive strain and degree of cure of resin was identified, indicating that the real-time compressive strain is proportional to the degree of cure of phenolic resin. By evaluating real-time curing shrinkage levels, the estimation of curing degree of phenolic resin can be achieved utilizing exponential correlation of curing degree and curing shrinkage level.