Novel carbazole based sensitizers for efficient dye-sensitized solar cells: Role of the hexyl chain

Jian Feng Huang; Jun Min Liu; Li Lin Tan; Yi Fan Chen; Yong Shen; Li Min Xiao; Dai Bin Kuang; Cheng Yong Su

doi:10.1016/j.dyepig.2014.10.022

Novel carbazole based sensitizers for efficient dye-sensitized solar cells: Role of the hexyl chain

Jian Feng Huang
, Jun Min Liu^*
, Li Lin Tan
, Yi Fan Chen
, Yong Shen
, Li Min Xiao
, Dai Bin Kuang
, Cheng Yong Su

^*此作品的通讯作者

计算机学院

Sun Yat-Sen University

科研成果: 期刊稿件 › 文章 › 同行评审

30 引用（Scopus）

摘要

Four novel D-D-π-A type organic dyes (DWH1-DWH4) were designed and synthesized, in which 3,6-bis(thiophene or hexylthiophene)-disubstituted carbazole moieties were used as the electron donor, bithiophene units or their derivatives as the π-conjugated bridge, and a cyanoacrylic acid group as the electron acceptor. The photovoltaic performance data indicate that the tuning of the J_sc and V_oc values can be conveniently accomplished by incorporation of long alkyl chains into sensitizer, which not only improves the molar extinction coefficients of the absorption and enhances the solubility but also increases the electron lifetime by leading to an effective spatial separation of the charges.

源语言	英语
页（从-至）	18-23
页数	6
期刊	Dyes and Pigments
卷	114
期	C
DOI	https://doi.org/10.1016/j.dyepig.2014.10.022
出版状态	已出版 - 3月 2015

联合国可持续发展目标

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可持续发展目标 7 经济适用的清洁能源

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10.1016/j.dyepig.2014.10.022

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title = "Novel carbazole based sensitizers for efficient dye-sensitized solar cells: Role of the hexyl chain",

abstract = "Four novel D-D-π-A type organic dyes (DWH1-DWH4) were designed and synthesized, in which 3,6-bis(thiophene or hexylthiophene)-disubstituted carbazole moieties were used as the electron donor, bithiophene units or their derivatives as the π-conjugated bridge, and a cyanoacrylic acid group as the electron acceptor. The photovoltaic performance data indicate that the tuning of the Jsc and Voc values can be conveniently accomplished by incorporation of long alkyl chains into sensitizer, which not only improves the molar extinction coefficients of the absorption and enhances the solubility but also increases the electron lifetime by leading to an effective spatial separation of the charges.",

keywords = "Carbazole, Dye-sensitized solar cells, Organic dye, Photovoltaic performance, The hexyl chain, Thiophene",

author = "Huang, \{Jian Feng\} and Liu, \{Jun Min\} and Tan, \{Li Lin\} and Chen, \{Yi Fan\} and Yong Shen and Xiao, \{Li Min\} and Kuang, \{Dai Bin\} and Su, \{Cheng Yong\}",

year = "2015",

month = mar,

doi = "10.1016/j.dyepig.2014.10.022",

language = "英语",

volume = "114",

pages = "18--23",

journal = "Dyes and Pigments",

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number = "C",

}

TY - JOUR

T1 - Novel carbazole based sensitizers for efficient dye-sensitized solar cells

T2 - Role of the hexyl chain

AU - Huang, Jian Feng

AU - Liu, Jun Min

AU - Tan, Li Lin

AU - Chen, Yi Fan

AU - Shen, Yong

AU - Xiao, Li Min

AU - Kuang, Dai Bin

AU - Su, Cheng Yong

PY - 2015/3

Y1 - 2015/3

N2 - Four novel D-D-π-A type organic dyes (DWH1-DWH4) were designed and synthesized, in which 3,6-bis(thiophene or hexylthiophene)-disubstituted carbazole moieties were used as the electron donor, bithiophene units or their derivatives as the π-conjugated bridge, and a cyanoacrylic acid group as the electron acceptor. The photovoltaic performance data indicate that the tuning of the Jsc and Voc values can be conveniently accomplished by incorporation of long alkyl chains into sensitizer, which not only improves the molar extinction coefficients of the absorption and enhances the solubility but also increases the electron lifetime by leading to an effective spatial separation of the charges.

AB - Four novel D-D-π-A type organic dyes (DWH1-DWH4) were designed and synthesized, in which 3,6-bis(thiophene or hexylthiophene)-disubstituted carbazole moieties were used as the electron donor, bithiophene units or their derivatives as the π-conjugated bridge, and a cyanoacrylic acid group as the electron acceptor. The photovoltaic performance data indicate that the tuning of the Jsc and Voc values can be conveniently accomplished by incorporation of long alkyl chains into sensitizer, which not only improves the molar extinction coefficients of the absorption and enhances the solubility but also increases the electron lifetime by leading to an effective spatial separation of the charges.

KW - Carbazole

KW - Dye-sensitized solar cells

KW - Organic dye

KW - Photovoltaic performance

KW - The hexyl chain

KW - Thiophene

UR - https://www.scopus.com/pages/publications/84925456900

U2 - 10.1016/j.dyepig.2014.10.022

DO - 10.1016/j.dyepig.2014.10.022

M3 - 文章

AN - SCOPUS:84925456900

SN - 0143-7208

VL - 114

SP - 18

EP - 23

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - C

ER -

Novel carbazole based sensitizers for efficient dye-sensitized solar cells: Role of the hexyl chain

摘要

联合国可持续发展目标

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