@inbook{bf97a150c5f145ae97c61b22bf604498,
title = "Nanoporous metal phosphate CoVSB-1 catalyst for oxidation of styrene with H2O2 ",
abstract = "Catalytic properties of nanoporous metal phosphates CoVSB-1 and VSB-1 were investigated in the selective oxidation of styrene to benzaldehyde with hydrogen peroxide as oxidant. The corresponding conversion and selectivity over calcined 52-CoVSB-1 were 35.7\% and 60.8\%, respectively. Whereas VSB-1, 11-CoVSB-1 and 31-CoVSB-1 show poor selectivity to benzaldehyde. The relationship between framework structure and the catalytic activity of CoVSB-1 was studied. It is found that the tetrahedral cobalt centers acted as active sites in the catalytic reaction and the increased basicity favored the formation of benzaldehyde. The behavior of P-OH and the coordination configurations of Co2+ and Ni2+ were studied through FT-IR and UV-vis methods.",
author = "Xie, \{L. L.\} and Gao, \{Q. M.\} and Li, \{Q. H.\}",
year = "2007",
doi = "10.1016/S0167-2991(07)80997-9",
language = "英语",
isbn = "0444530681",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier Inc.",
number = "B",
pages = "1338--1343",
booktitle = "From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference",
address = "美国",
edition = "B",
}