Isothermal oxidation behavior of dysprosium/S-Doped β-NiAl alloys at 1200 °C

A β-NiAl alloy with normal purity, a S-doped and a Dy and S co-doped β-NiAl alloys were prepared by arc-melting and their corresponding S contents were less than 20×10^-6, 33×10^-6 and 22×10^-6, respectively. The isothermal oxidation behavior of the alloys at 1200°C was investigated and the extent of S segregation at the scale-alloy interface was determined by scanning Auger microscopy. S-doping had no significant effect on the phase transformation rate from θ- to α-Al₂O₃, while the addition of Dy retarded this process. For the S-doped alloy, scale rumpling occurred only after 2h thermal exposure and numerous large voids were observed at the scale-alloy interface where S segregated. In contrast to this, the oxide scale formed on the Dy and S co-doped alloy still remained flat even after 50h isothermal oxidation and only small voids existed at the interface where S segregation was not detected.