Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes

Teng Wang; Shi Kai Xiang; Chong Qin; Jun An Ma; Li He Zhang; Ning Jiao

doi:10.1016/j.tetlet.2011.04.041

Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes

Teng Wang
, Shi Kai Xiang
, Chong Qin
, Jun An Ma
, Li He Zhang
, Ning Jiao^*

^*此作品的通讯作者

Tianjin University
Peking University
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

16 引用（Scopus）

摘要

A direct oxidative approach to alkenyl aldehydes from allyl arenes via allyl sp³ C-H functionalization was disclosed. An inexpensive iron catalyst was employed to facilitate this transformation. The mechanistic studies indicate that the cleavage of the allyl sp³ C-H bond is involved in the rate-determining step.

源语言	英语
页（从-至）	3208-3211
页数	4
期刊	Tetrahedron Letters
卷	52
期	25
DOI	https://doi.org/10.1016/j.tetlet.2011.04.041
出版状态	已出版 - 22 6月 2011
已对外发布	是

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10.1016/j.tetlet.2011.04.041

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title = "Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes",

abstract = "A direct oxidative approach to alkenyl aldehydes from allyl arenes via allyl sp3 C-H functionalization was disclosed. An inexpensive iron catalyst was employed to facilitate this transformation. The mechanistic studies indicate that the cleavage of the allyl sp3 C-H bond is involved in the rate-determining step.",

author = "Teng Wang and Xiang, \{Shi Kai\} and Chong Qin and Ma, \{Jun An\} and Zhang, \{Li He\} and Ning Jiao",

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T1 - Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes

AU - Wang, Teng

AU - Xiang, Shi Kai

AU - Qin, Chong

AU - Ma, Jun An

AU - Zhang, Li He

AU - Jiao, Ning

PY - 2011/6/22

Y1 - 2011/6/22

N2 - A direct oxidative approach to alkenyl aldehydes from allyl arenes via allyl sp3 C-H functionalization was disclosed. An inexpensive iron catalyst was employed to facilitate this transformation. The mechanistic studies indicate that the cleavage of the allyl sp3 C-H bond is involved in the rate-determining step.

AB - A direct oxidative approach to alkenyl aldehydes from allyl arenes via allyl sp3 C-H functionalization was disclosed. An inexpensive iron catalyst was employed to facilitate this transformation. The mechanistic studies indicate that the cleavage of the allyl sp3 C-H bond is involved in the rate-determining step.

UR - https://www.scopus.com/pages/publications/79956223488

U2 - 10.1016/j.tetlet.2011.04.041

DO - 10.1016/j.tetlet.2011.04.041

M3 - 文章

AN - SCOPUS:79956223488

SN - 0040-4039

VL - 52

SP - 3208

EP - 3211

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 25

ER -

Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes

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