In-situ constructed three-dimensional MoS₂–MoN heterostructure as the cathode of lithium–sulfur battery

Lithium–sulfur batteries are recognized as one of the most promising next-generation high-performance energy storage systems. However, obstacles like the irreversible capacity loss hinder its broad application. Herein, we fabricated an interconnected three-dimensional MoS₂–MoN heterostructure (3D-MoS₂–MoN) via a facile salt-template method, overcoming the intrinsic shortcomings such as poor conductivity and compact morphology of traditionally-synthesized transition metal sulfides (TMSs). Furthermore, excellent electrocatalysis ability and hierarchical pore structure effectively accelerate the sluggish lithium polysulfides conversions during cycling. As a result, 3D-MoS₂–MoN showed a high initial specific capacity of 1466 mAh·g⁻¹ and excellent high-rate capability up to 4 °C. A stable cycling performance with a sulfur loading of 2 mg·cm⁻² was realized with a low decay rate of 0.069% per cycle. This work introduced a rational design route for the appliance of TMSs in the lithium-sulfur batteries. Graphic abstract: [Figure not available: see fulltext.]