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HPW/MCM-41 mesoporous silica composites as novel proton exchange membranes for elevated temperature fuel cells

  • Shanfu Lu
  • , Deli Wang
  • , Jinlin Lu
  • , Jie Zeng
  • , San Ping Jiang
  • Nanyang Technological University

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

摘要

A novel inorganic proton exchange electrolyte based on highly ordered mesoporous MCM-41 silica with assembled phosphotungstic acid is synthesized through vacuum-assisted impregnation method. The structure and physical properties of the electrolytes before and after impregnation were characterized and compared with conventional impregnated method by using TEM, SAXS, FT-IR and BET method. The proton conductivity of the electrolytes obtained by vacuum-assisted impregnation is 0.018 S cm-1 and 0.045 S cm -1 at 25 °C and 150 °C, respectively. The cell based on the inorganic proton exchange membrane achieved a power density of 95 mW cm -2 in a H2/O2 at 100 °C and 100% RH, and 90 mW cm-2 in methanol/O2 at 150 °C and 0.67% RH.

源语言英语
主期刊名ECS Transactions -Proton Exchange Membrane Fuel Cells 9
页1927-1933
页数7
版本1 PART 2
DOI
出版状态已出版 - 2009
已对外发布是
活动9th Proton Exchange Membrane Fuel Cell Symposium (PEMFC 9) - 216th Meeting of the Electrochemical Society - Vienna, 奥地利
期限: 4 10月 2009 → 9 10月 2009

丛书

姓名ECS Transactions
编号1 PART 2
卷25
ISSN(印刷版)1938-5862
ISSN(电子版)1938-6737

会议

会议9th Proton Exchange Membrane Fuel Cell Symposium (PEMFC 9) - 216th Meeting of the Electrochemical Society
国家/地区奥地利
市Vienna
时期4/10/09 → 9/10/09

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