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Electrodeposition of ZnO nanocrystallines on ITO mesoporous films and application to photoelectrochemical cells

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

ZnO nanocrystallines doped indium-tin-oxide (ITO) mesoporous films were prepared by electrodepositing ZnO nanocrystallines on ITO mesoporous films in the electrolyte of 0.1 M Zn(NO3)2. To function as a photoelecrrode, the CdS quantum dots as sensitizers were synthesized on the surface of ZnO nanocrystallines doped ITO mesoporous films. Both SEM and TEM images showed that ZnO nanocrystallines were successfully electrodeposited on the ITO mesoporous films. XRD pattern and selective area electron diffraction pattern revealed that the ZnO nanocrystallines were hexagonal (wurtzite) phase. The results of UV-Vis adsorption spectra analysis demonstrated that absorbance in visible region was enhanced with the deposition of ZnO and CdS on ITO mesoporous films. Photocurrent-voltage measurement results indicated that the ITO mesoporous film/ZnO/CdS photoelectrodes were efficient as a working electrode and its performance was superior to that of ITO mesoporous film/CdS photoelecrrodes because of the suppression of recombination by ZnO coating.

源语言英语
主期刊名Materials Processing and Energy Materials
出版商Minerals, Metals and Materials Society
465-472
页数8
ISBN(印刷版)9781118029459
DOI
出版状态已出版 - 2011

出版系列

姓名TMS Annual Meeting
1

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