Effects of surface modification on thermal cycling lifetime of thermal barrier coatings with HVOF NiCrAlY bond coat

NiCrAlY bond coat was prepared by HVOF (high-velocity oxygen fuel) spray on nickel-based superalloy. Surface treatments like grit-blasting, shot-peening and vacuum treatment methods were carried out in order to study the effects of surface modification on thermal cycling lifetime of TBCs. The surface-modified TBCs exhibited better thermal shock resistance. Failure of TBCs with the as-sprayed bond coat occurred within the top coat and at the interface between spinels and the top coat, while that of after shot-peening, grit-blasting and vacuum treatment occurred mainly within the top coat. TGO (thermally grown oxide) formed on as-sprayed bond coat was composed of a Ni(Al,Cr)₂O₄ spinels outer layer and a Al₂O₃ inner layer. But, a continuous and uniform Al₂O₃ formed after surface modification. Formation of the mixed oxides (spinels) on the as-sprayed bond coat accelerated the failure of TBCs.