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Effect of pH value on stress corrosion cracking of X70 pipeline steel in acidic soil environment

  • Zhiyong Liu
  • , Cuiwei Du
  • , Xin Zhang
  • , Fuming Wang
  • , Xiaogang Li*
  • *此作品的通讯作者
  • University of Science and Technology Beijing
  • Ministry of Ecology and Environment

科研成果: 期刊稿件文章同行评审

摘要

The effect of pH value on the stress corrosion cracking (SCC) of API X70 pipeline steel in simulated acidic soil solutions was investigated by using slow strain rate test, electrochemical polarization curves, electrochemical impedance spectroscopy, and scanning electron microscopy. pH plays an important role in the susceptibility and electrochemical mechanism of SCC. The pH higher than 5 has no significant effect on electrochemical processes. By contrast, the pH lower than 5 intensifies cathodic hydrogen evolution reactions, thus increasing the cathodic current and corrosion potential. Under different pH values, the SCC mechanism of X70 pipeline steel varies among anodic dissolution (AD), hydrogen embrittlement (HE), and the combination of AD and HE (AD + HE) with variations of applied potential. At -850 mVSCE, the SCC mechanism is HE if pH is less than 4 or AD + HE if pH value is more positive.

源语言英语
页(从-至)489-496
页数8
期刊Acta Metallurgica Sinica (English Letters)
26
4
DOI
出版状态已出版 - 8月 2013
已对外发布

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