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Cross-linked alternately copolymerized electrolyte poly (styrene-a-maleic ester) synthesized through solvent-free strategy

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

A solvent-free cross-linked alternating copolymer electrolyte is synthesized through photo copolymerization of comb-like poly (ethylene glycol) ester maleate and styrene. Phase transitions, thermal properties, ionic conductivities and electrochemical stabilities are investigated to characterize the alternating copolymer electrolyte. The flexible solid polymer electrolyte (spe) with lithium salt content of 15 wt.% and MA/-OH = 1 has a good ionic conductivity of 1.45×10-5 S cm-1 at 35 °C and a superior electrochemical stability to 5.2 V. The maleic anhydride on the main chain increases the rigidity of the copolymer matrix and decreases the ionic conductivity.

源语言英语
主期刊名Applied Mechanics and Materials II
1196-1204
页数9
DOI
出版状态已出版 - 2014
活动2013 2nd International Conference on Applied Mechanics and Materials, ICAMM 2013 - Zhuhai, 中国
期限: 23 11月 201324 11月 2013

出版系列

姓名Applied Mechanics and Materials
477-478
ISSN(印刷版)1660-9336
ISSN(电子版)1662-7482

会议

会议2013 2nd International Conference on Applied Mechanics and Materials, ICAMM 2013
国家/地区中国
Zhuhai
时期23/11/1324/11/13

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