Copper-catalyzed oxidative transformation of aryl propargylic azides to aryl propiolonitriles

Teng Wang; Hang Yin; Ning Jiao

doi:10.1002/adsc.201201056

Copper-catalyzed oxidative transformation of aryl propargylic azides to aryl propiolonitriles

Teng Wang
, Hang Yin
, Ning Jiao^*

^*此作品的通讯作者

Peking University
Tianjin University
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.

源语言	英语
页（从-至）	1207-1210
页数	4
期刊	Advanced Synthesis and Catalysis
卷	355
期	6
DOI	https://doi.org/10.1002/adsc.201201056
出版状态	已出版 - 15 4月 2013
已对外发布	是

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title = "Copper-catalyzed oxidative transformation of aryl propargylic azides to aryl propiolonitriles",

abstract = "A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.",

keywords = "Schmidt rearrangement, azides, copper, dehydrogenation, nitriles, oxidation",

author = "Teng Wang and Hang Yin and Ning Jiao",

year = "2013",

month = apr,

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doi = "10.1002/adsc.201201056",

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T1 - Copper-catalyzed oxidative transformation of aryl propargylic azides to aryl propiolonitriles

AU - Wang, Teng

AU - Yin, Hang

AU - Jiao, Ning

PY - 2013/4/15

Y1 - 2013/4/15

N2 - A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.

AB - A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.

KW - Schmidt rearrangement

KW - azides

KW - copper

KW - dehydrogenation

KW - nitriles

KW - oxidation

UR - https://www.scopus.com/pages/publications/84876486975

U2 - 10.1002/adsc.201201056

DO - 10.1002/adsc.201201056

M3 - 文章

AN - SCOPUS:84876486975

SN - 1615-4150

VL - 355

SP - 1207

EP - 1210

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 6

ER -

Copper-catalyzed oxidative transformation of aryl propargylic azides to aryl propiolonitriles

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