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Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts?

  • Rafael B. Rosante
  • , Ricardo F. Lancelotti
  • , Donald B. Dingwell
  • , Edgar D. Zanotto
  • , Luiz Pereira*
  • *此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

Borosilicate glasses and glass-ceramics are widely used in laboratory, optical, display, and nuclear technologies. Their viscosity–temperature relationship governs key processing steps such as melting, sintering, and crystallization. Here, viscosity–temperature data for various borosilicate compositions were compiled and analyzed using three models: Vogel–Fulcher–Tammann (VFT), Avramov–Milchev (AM), and Mauro–Yue–Ellison–Gupta–Allan (MYEGA). Statistical evaluation shows that AM and MYEGA outperform VFT in extrapolating partial datasets, with low-temperature data yielding superior predictions at higher temperatures. We also determine the infinite-temperature viscosity value for each model and identify compositions whose partial datasets successfully reproduce the full viscosity–temperature curve. A new dimensionless parameter (φ) is introduced to assess extrapolation reliability. Including the calorimetric glass transition temperature significantly improves the accuracy of extrapolated data. These findings provide a practical framework for optimizing viscosity experiments and predicting the complete viscosity–temperature behavior of borosilicate melts.

源语言英语
文章编号124047
期刊Journal of Non-Crystalline Solids
681
DOI
出版状态已出版 - 15 5月 2026

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