TY - JOUR
T1 - Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts?
AU - Rosante, Rafael B.
AU - Lancelotti, Ricardo F.
AU - Dingwell, Donald B.
AU - Zanotto, Edgar D.
AU - Pereira, Luiz
N1 - Publisher Copyright:
© 2026 Elsevier B.V.
PY - 2026/5/15
Y1 - 2026/5/15
N2 - Borosilicate glasses and glass-ceramics are widely used in laboratory, optical, display, and nuclear technologies. Their viscosity–temperature relationship governs key processing steps such as melting, sintering, and crystallization. Here, viscosity–temperature data for various borosilicate compositions were compiled and analyzed using three models: Vogel–Fulcher–Tammann (VFT), Avramov–Milchev (AM), and Mauro–Yue–Ellison–Gupta–Allan (MYEGA). Statistical evaluation shows that AM and MYEGA outperform VFT in extrapolating partial datasets, with low-temperature data yielding superior predictions at higher temperatures. We also determine the infinite-temperature viscosity value for each model and identify compositions whose partial datasets successfully reproduce the full viscosity–temperature curve. A new dimensionless parameter (φ) is introduced to assess extrapolation reliability. Including the calorimetric glass transition temperature significantly improves the accuracy of extrapolated data. These findings provide a practical framework for optimizing viscosity experiments and predicting the complete viscosity–temperature behavior of borosilicate melts.
AB - Borosilicate glasses and glass-ceramics are widely used in laboratory, optical, display, and nuclear technologies. Their viscosity–temperature relationship governs key processing steps such as melting, sintering, and crystallization. Here, viscosity–temperature data for various borosilicate compositions were compiled and analyzed using three models: Vogel–Fulcher–Tammann (VFT), Avramov–Milchev (AM), and Mauro–Yue–Ellison–Gupta–Allan (MYEGA). Statistical evaluation shows that AM and MYEGA outperform VFT in extrapolating partial datasets, with low-temperature data yielding superior predictions at higher temperatures. We also determine the infinite-temperature viscosity value for each model and identify compositions whose partial datasets successfully reproduce the full viscosity–temperature curve. A new dimensionless parameter (φ) is introduced to assess extrapolation reliability. Including the calorimetric glass transition temperature significantly improves the accuracy of extrapolated data. These findings provide a practical framework for optimizing viscosity experiments and predicting the complete viscosity–temperature behavior of borosilicate melts.
KW - Extrapolation reliability
KW - Glass
KW - Nuclear waste vitrification
KW - Rheology
KW - Viscosity models
UR - https://www.scopus.com/pages/publications/105031709636
U2 - 10.1016/j.jnoncrysol.2026.124047
DO - 10.1016/j.jnoncrysol.2026.124047
M3 - 文章
AN - SCOPUS:105031709636
SN - 0022-3093
VL - 681
JO - Journal of Non-Crystalline Solids
JF - Journal of Non-Crystalline Solids
M1 - 124047
ER -