Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides

Yan Li; Lin Tan; Zhaohui Wang; Hualei Qian; Yubai Shi; Wenping Hu

doi:10.1021/ol703046w

Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides

Yan Li
, Lin Tan
, Zhaohui Wang^*
, Hualei Qian
, Yubai Shi
, Wenping Hu

^*此作品的通讯作者

CAS - Institute of Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

129 引用（Scopus）

摘要

A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

源语言	英语
页（从-至）	529-532
页数	4
期刊	Organic Letters
卷	10
期	4
DOI	https://doi.org/10.1021/ol703046w
出版状态	已出版 - 21 2月 2008
已对外发布	是

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abstract = "A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.",

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T2 - Core-perfluoroalkylated perylene bisimides

AU - Li, Yan

AU - Tan, Lin

AU - Wang, Zhaohui

AU - Qian, Hualei

AU - Shi, Yubai

AU - Hu, Wenping

PY - 2008/2/21

Y1 - 2008/2/21

N2 - A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

AB - A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

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M3 - 文章

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Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides

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