A Butterfly-Inspired Hierarchical Light-Trapping Structure towards a High-Performance Polarization-Sensitive Perovskite Photodetector

Extensive applications for photodetectors have led to demand for high-responsivity polarization-sensitive light detection. Inspired by the elaborate architecture of butterfly Papilio paris, a 1D nanograting bonded porous 2D photonic crystal perovskite photodetector (G-PC-PD) using a commercial DVD master and 2D crystalline colloidal arrays template was fabricated. The coupling effect from grating diffraction and reflection of the PC stopband renders the enhanced light harvesting of G-PC-PD. The porous scaffold and nanoimprinting process afford a highly crystalline perovskite film. White light responsivity and detectivity of G-PC-PD are up to 12.67 A W⁻¹ and 3.22×10¹³ Jones (6∼7 times that of a pristine perovskite photodetector). The highly ordered nanograting arrays of G-PC-PD enable polarization-sensitive light detection with a rate of −0.72 nA deg⁻¹. This hierarchical perovskite integrated nanograting and 2D PC architecture opens a new avenue to high-performance optoelectronic devices.