UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes

Ruixing Li; Shinryo Yabe; Mika Yamashita; Shigeyosi Momose; Sakae Yoshida; Shu Yin; Tsugio Sato

doi:10.1016/S0254-0584(02)00027-5

UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes

Ruixing Li
, Shinryo Yabe
, Mika Yamashita
, Shigeyosi Momose
, Sakae Yoshida
, Shu Yin
, Tsugio Sato^*

^*Corresponding author for this work

Tohoku University
KOSÉ Corporation
Nippon Inorganic Colour and Chemical Co. Ltd.

Research output: Contribution to journal › Conference article › peer-review

147 Scopus citations

Abstract

Nanoparticles of zinc oxide-doped ceria (3-7 nm diameter) were synthesized by soft solution chemical processes at 40 °C and pH 6. Some zinc ions remained in the solution but cerium ions precipitated completely at pH 6. The solubility limit of ZnO in Ce_1-xZn_xO_2-x was determined to be x = 0.561. The oxidation catalytic activity of ceria effectively decreased by doping with zinc oxide. The photocatalytic activity of undoped ceria and zinc oxide-doped ceria for oxidation of phenol was much smaller than that of titania. Zinc oxide-doped ceria showed excellent UV absorption and transparency in the visible ray region in a similar manner as that of undoped ceria.

Original language	English
Pages (from-to)	39-44
Number of pages	6
Journal	Materials Chemistry and Physics
Volume	75
Issue number	1-3
DOIs	https://doi.org/10.1016/S0254-0584(02)00027-5
State	Published - 28 Apr 2002
Externally published	Yes
Event	ICMAT 2001 Symposium C (Novel and Advanced Ceramics) - Singapore, Singapore Duration: 28 Apr 2002 → …

Keywords

Catalytic activity
Ceria
Fine powder
Solid solution
UV-shielding
Zinc oxide

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10.1016/S0254-0584(02)00027-5

Cite this

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title = "UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes",

abstract = "Nanoparticles of zinc oxide-doped ceria (3-7 nm diameter) were synthesized by soft solution chemical processes at 40 °C and pH 6. Some zinc ions remained in the solution but cerium ions precipitated completely at pH 6. The solubility limit of ZnO in Ce1-xZnxO2-x was determined to be x = 0.561. The oxidation catalytic activity of ceria effectively decreased by doping with zinc oxide. The photocatalytic activity of undoped ceria and zinc oxide-doped ceria for oxidation of phenol was much smaller than that of titania. Zinc oxide-doped ceria showed excellent UV absorption and transparency in the visible ray region in a similar manner as that of undoped ceria.",

keywords = "Catalytic activity, Ceria, Fine powder, Solid solution, UV-shielding, Zinc oxide",

author = "Ruixing Li and Shinryo Yabe and Mika Yamashita and Shigeyosi Momose and Sakae Yoshida and Shu Yin and Tsugio Sato",

year = "2002",

month = apr,

day = "28",

doi = "10.1016/S0254-0584(02)00027-5",

language = "英语",

volume = "75",

pages = "39--44",

journal = "Materials Chemistry and Physics",

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publisher = "Elsevier B.V.",

number = "1-3",

note = "ICMAT 2001 Symposium C (Novel and Advanced Ceramics) ; Conference date: 28-04-2002",

}

TY - JOUR

T1 - UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes

AU - Li, Ruixing

AU - Yabe, Shinryo

AU - Yamashita, Mika

AU - Momose, Shigeyosi

AU - Yoshida, Sakae

AU - Yin, Shu

AU - Sato, Tsugio

PY - 2002/4/28

Y1 - 2002/4/28

N2 - Nanoparticles of zinc oxide-doped ceria (3-7 nm diameter) were synthesized by soft solution chemical processes at 40 °C and pH 6. Some zinc ions remained in the solution but cerium ions precipitated completely at pH 6. The solubility limit of ZnO in Ce1-xZnxO2-x was determined to be x = 0.561. The oxidation catalytic activity of ceria effectively decreased by doping with zinc oxide. The photocatalytic activity of undoped ceria and zinc oxide-doped ceria for oxidation of phenol was much smaller than that of titania. Zinc oxide-doped ceria showed excellent UV absorption and transparency in the visible ray region in a similar manner as that of undoped ceria.

AB - Nanoparticles of zinc oxide-doped ceria (3-7 nm diameter) were synthesized by soft solution chemical processes at 40 °C and pH 6. Some zinc ions remained in the solution but cerium ions precipitated completely at pH 6. The solubility limit of ZnO in Ce1-xZnxO2-x was determined to be x = 0.561. The oxidation catalytic activity of ceria effectively decreased by doping with zinc oxide. The photocatalytic activity of undoped ceria and zinc oxide-doped ceria for oxidation of phenol was much smaller than that of titania. Zinc oxide-doped ceria showed excellent UV absorption and transparency in the visible ray region in a similar manner as that of undoped ceria.

KW - Catalytic activity

KW - Ceria

KW - Fine powder

KW - Solid solution

KW - UV-shielding

KW - Zinc oxide

UR - https://www.scopus.com/pages/publications/0037188163

U2 - 10.1016/S0254-0584(02)00027-5

DO - 10.1016/S0254-0584(02)00027-5

M3 - 会议文章

AN - SCOPUS:0037188163

SN - 0254-0584

VL - 75

SP - 39

EP - 44

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

IS - 1-3

T2 - ICMAT 2001 Symposium C (Novel and Advanced Ceramics)

Y2 - 28 April 2002

ER -

UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes

Abstract

Keywords

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