Theory of non-linear susceptibility and correlation length in glasses and liquids

  • Claudio Donati
  • , Silvio Franz*
  • , Sharon C. Glotzer
  • , Giorgio Parisi
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Within the framework of the effective potential theory of the structural glass transition, we calculate for the p-spin model and for a hard sphere liquid in the hypernetted chain approximation a static non-linear susceptibility related to a four-point density correlation function, and show that it diverges in mean field with exponent γ = 1/2 as the critical temperature Tc is approached from below. When Tc is approached from above, we calculate for the p-spin model a time dependent non-linear susceptibility and show that there is a characteristic time where this susceptibility has a maximum, and that this time grows with decreasing T. This susceptibility diverges as Tc is approached from above, and has key features in common with a generalized susceptibility related to particle displacements, previously introduced to measure correlated particle motion in simulations of glass-forming liquids.

Original languageEnglish
Pages (from-to)215-224
Number of pages10
JournalJournal of Non-Crystalline Solids
Volume307-310
DOIs
StatePublished - Sep 2002
Externally publishedYes

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