The synthesis and characterization of a two-dimensional cobalt-zinc phosphate: NH4[Zn2-xCox(PO4)(HPO4)] (x ≈ 0.12)

Qiuming Gao; Ann M. Chippindale; Andrew R. Cowley; Jiesheng Chen; Ruren Xu

doi:10.1021/jp972134d

The synthesis and characterization of a two-dimensional cobalt-zinc phosphate: NH₄[Zn_2-xCo_x(PO₄)(HPO₄)] (x ≈ 0.12)

Qiuming Gao
, Ann M. Chippindale^*
, Andrew R. Cowley
, Jiesheng Chen
, Ruren Xu

^*Corresponding author for this work

Jilin University
University of Oxford

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A new layered ammonium cobalt-zinc phosphate has been synthesized under solvothermal conditions at 160°C and the structure solved using room-temperature single-crystal X-ray diffraction data. (NH₄[Zn_2-xCO_x(PO₄)(HPO₄)] (x ≈ 0.12), M_r = 339.75, triclinic, space group P-1, a = 5.237(1) Å, b = 8.949(1) Å³, c = 9.728(1) Å, α = 74.99(1)°, β = 77.64(1)°, γ = 72.92(1)°, V = 416.19(1) Å³, Z = 2, 1511 observed data measured with I > 3σ(I), R = 4.31% and R_w = 4.67%). The structure consists of MO₄ (M = Zn, Co), PO₄, and PO₃(OH) tetrahedra linked to form buckled layers containing three- and four-membered rings between which ammonium cations reside. A network of hydrogen bonds involving both interlayer and layer-to-ammonium interactions holds the phosphate layers together.

Original language	English
Pages (from-to)	9940-9942
Number of pages	3
Journal	Journal of Physical Chemistry B
Volume	101
Issue number	48
DOIs	https://doi.org/10.1021/jp972134d
State	Published - 27 Nov 1997
Externally published	Yes

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title = "The synthesis and characterization of a two-dimensional cobalt-zinc phosphate: NH4[Zn2-xCox(PO4)(HPO4)] (x ≈ 0.12)",

abstract = "A new layered ammonium cobalt-zinc phosphate has been synthesized under solvothermal conditions at 160°C and the structure solved using room-temperature single-crystal X-ray diffraction data. (NH4[Zn2-xCOx(PO4)(HPO4)] (x ≈ 0.12), Mr = 339.75, triclinic, space group P-1, a = 5.237(1) {\AA}, b = 8.949(1) {\AA}3, c = 9.728(1) {\AA}, α = 74.99(1)°, β = 77.64(1)°, γ = 72.92(1)°, V = 416.19(1) {\AA}3, Z = 2, 1511 observed data measured with I > 3σ(I), R = 4.31\% and Rw = 4.67\%). The structure consists of MO4 (M = Zn, Co), PO4, and PO3(OH) tetrahedra linked to form buckled layers containing three- and four-membered rings between which ammonium cations reside. A network of hydrogen bonds involving both interlayer and layer-to-ammonium interactions holds the phosphate layers together.",

author = "Qiuming Gao and Chippindale, \{Ann M.\} and Cowley, \{Andrew R.\} and Jiesheng Chen and Ruren Xu",

year = "1997",

month = nov,

day = "27",

doi = "10.1021/jp972134d",

language = "英语",

volume = "101",

pages = "9940--9942",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

number = "48",

}

TY - JOUR

T1 - The synthesis and characterization of a two-dimensional cobalt-zinc phosphate

T2 - NH4[Zn2-xCox(PO4)(HPO4)] (x ≈ 0.12)

AU - Gao, Qiuming

AU - Chippindale, Ann M.

AU - Cowley, Andrew R.

AU - Chen, Jiesheng

AU - Xu, Ruren

PY - 1997/11/27

Y1 - 1997/11/27

N2 - A new layered ammonium cobalt-zinc phosphate has been synthesized under solvothermal conditions at 160°C and the structure solved using room-temperature single-crystal X-ray diffraction data. (NH4[Zn2-xCOx(PO4)(HPO4)] (x ≈ 0.12), Mr = 339.75, triclinic, space group P-1, a = 5.237(1) Å, b = 8.949(1) Å3, c = 9.728(1) Å, α = 74.99(1)°, β = 77.64(1)°, γ = 72.92(1)°, V = 416.19(1) Å3, Z = 2, 1511 observed data measured with I > 3σ(I), R = 4.31% and Rw = 4.67%). The structure consists of MO4 (M = Zn, Co), PO4, and PO3(OH) tetrahedra linked to form buckled layers containing three- and four-membered rings between which ammonium cations reside. A network of hydrogen bonds involving both interlayer and layer-to-ammonium interactions holds the phosphate layers together.

AB - A new layered ammonium cobalt-zinc phosphate has been synthesized under solvothermal conditions at 160°C and the structure solved using room-temperature single-crystal X-ray diffraction data. (NH4[Zn2-xCOx(PO4)(HPO4)] (x ≈ 0.12), Mr = 339.75, triclinic, space group P-1, a = 5.237(1) Å, b = 8.949(1) Å3, c = 9.728(1) Å, α = 74.99(1)°, β = 77.64(1)°, γ = 72.92(1)°, V = 416.19(1) Å3, Z = 2, 1511 observed data measured with I > 3σ(I), R = 4.31% and Rw = 4.67%). The structure consists of MO4 (M = Zn, Co), PO4, and PO3(OH) tetrahedra linked to form buckled layers containing three- and four-membered rings between which ammonium cations reside. A network of hydrogen bonds involving both interlayer and layer-to-ammonium interactions holds the phosphate layers together.

UR - https://www.scopus.com/pages/publications/0031269568

U2 - 10.1021/jp972134d

DO - 10.1021/jp972134d

M3 - 文章

AN - SCOPUS:0031269568

SN - 1520-6106

VL - 101

SP - 9940

EP - 9942

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 48

ER -

The synthesis and characterization of a two-dimensional cobalt-zinc phosphate: NH₄[Zn_2-xCo_x(PO₄)(HPO₄)] (x ≈ 0.12)

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