Abstract
We have synthesized a single-phase Sr2CuO3+δ superconductor of Tc 75 K with K2NiF4 structure under high-pressure showing so far rarely formed partially occupied "apical oxygen" which also acts as the dopant. After post annealing the as-prepared sample from 150 °C to 300 °C at ambient, the superconducting transition temperature (Tc) could be systematically enhanced up to 95 K. Transmission electron microscopy (TEM) measurements on the Sr2CuO3+δ superconductors revealed a series of modulated structure phenomena resulting from dopant ordering. The distribution geometry of dopant such as the partially occupied apical oxygen here can be an additional route to reach further higher Tc.
| Original language | English |
|---|---|
| Pages (from-to) | 100-102 |
| Number of pages | 3 |
| Journal | Physica C: Superconductivity and its Applications |
| Volume | 463-465 |
| Issue number | SUPPL. |
| DOIs | |
| State | Published - 1 Oct 2007 |
| Externally published | Yes |
Keywords
- Apical oxygen ordering
- High T superconductor
- High-pressure synthesis
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