The relationship between t-ZrO 2 stability and the crystallization of a Zr-based bulk metallic glass during oxidation

Dongya Huang; Lu Huang; Bin Wang; Vincent Ji; Tao Zhang

doi:10.1016/j.intermet.2012.05.009

The relationship between t-ZrO ₂ stability and the crystallization of a Zr-based bulk metallic glass during oxidation

Dongya Huang
, Lu Huang
, Bin Wang
, Vincent Ji
, Tao Zhang^*

^*Corresponding author for this work

School of Materials Science and Engineering

Beihang University
Institut de Chimie Moléculaire et des Matériaux d'Orsay

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The tetragonal ZrO ₂ is observed in the oxidation surface of Zr ₅₅Cu ₃₀Al ₁₀Ni ₅ bulk metallic glass (BMG) while both the tetragonal ZrO ₂ (t-ZrO ₂) and monoclinic ZrO ₂ (m-ZrO ₂) are determined on the oxidation surface of crystalline counterparts with same chemical composition. In vacuum, the phase transformation of t-ZrO ₂ into m-ZrO ₂ in the oxide scale is investigated on the BMG substrate and crystalline substrate, both annealed at different temperatures, respectively. The crystallization of BMG substrate is related to the formation of m-ZrO ₂. The difference of the diffusion mechanism in the oxidation of bulk metallic glass and its crystalline alloy is characterized by ¹⁸O ₂ isotopic tracer. In the oxidation, the promotion of m-ZrO ₂ on the crystalline substrate is attributed to the inward diffusion of oxygen.

Original language	English
Pages (from-to)	21-25
Number of pages	5
Journal	Intermetallics
Volume	31
DOIs	https://doi.org/10.1016/j.intermet.2012.05.009
State	Published - Dec 2012

Keywords

B. Diffusion
B. Glasses, metallic
B. Oxidation
F. Secondary ion mass spectrometry

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10.1016/j.intermet.2012.05.009

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@article{b193f5177d264ca5a15b980b66a37a25,

title = "The relationship between t-ZrO 2 stability and the crystallization of a Zr-based bulk metallic glass during oxidation",

abstract = "The tetragonal ZrO 2 is observed in the oxidation surface of Zr 55Cu 30Al 10Ni 5 bulk metallic glass (BMG) while both the tetragonal ZrO 2 (t-ZrO 2) and monoclinic ZrO 2 (m-ZrO 2) are determined on the oxidation surface of crystalline counterparts with same chemical composition. In vacuum, the phase transformation of t-ZrO 2 into m-ZrO 2 in the oxide scale is investigated on the BMG substrate and crystalline substrate, both annealed at different temperatures, respectively. The crystallization of BMG substrate is related to the formation of m-ZrO 2. The difference of the diffusion mechanism in the oxidation of bulk metallic glass and its crystalline alloy is characterized by 18O 2 isotopic tracer. In the oxidation, the promotion of m-ZrO 2 on the crystalline substrate is attributed to the inward diffusion of oxygen.",

keywords = "B. Diffusion, B. Glasses, metallic, B. Oxidation, F. Secondary ion mass spectrometry",

author = "Dongya Huang and Lu Huang and Bin Wang and Vincent Ji and Tao Zhang",

year = "2012",

month = dec,

doi = "10.1016/j.intermet.2012.05.009",

language = "英语",

volume = "31",

pages = "21--25",

journal = "Intermetallics",

issn = "0966-9795",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - The relationship between t-ZrO 2 stability and the crystallization of a Zr-based bulk metallic glass during oxidation

AU - Huang, Dongya

AU - Huang, Lu

AU - Wang, Bin

AU - Ji, Vincent

AU - Zhang, Tao

PY - 2012/12

Y1 - 2012/12

N2 - The tetragonal ZrO 2 is observed in the oxidation surface of Zr 55Cu 30Al 10Ni 5 bulk metallic glass (BMG) while both the tetragonal ZrO 2 (t-ZrO 2) and monoclinic ZrO 2 (m-ZrO 2) are determined on the oxidation surface of crystalline counterparts with same chemical composition. In vacuum, the phase transformation of t-ZrO 2 into m-ZrO 2 in the oxide scale is investigated on the BMG substrate and crystalline substrate, both annealed at different temperatures, respectively. The crystallization of BMG substrate is related to the formation of m-ZrO 2. The difference of the diffusion mechanism in the oxidation of bulk metallic glass and its crystalline alloy is characterized by 18O 2 isotopic tracer. In the oxidation, the promotion of m-ZrO 2 on the crystalline substrate is attributed to the inward diffusion of oxygen.

AB - The tetragonal ZrO 2 is observed in the oxidation surface of Zr 55Cu 30Al 10Ni 5 bulk metallic glass (BMG) while both the tetragonal ZrO 2 (t-ZrO 2) and monoclinic ZrO 2 (m-ZrO 2) are determined on the oxidation surface of crystalline counterparts with same chemical composition. In vacuum, the phase transformation of t-ZrO 2 into m-ZrO 2 in the oxide scale is investigated on the BMG substrate and crystalline substrate, both annealed at different temperatures, respectively. The crystallization of BMG substrate is related to the formation of m-ZrO 2. The difference of the diffusion mechanism in the oxidation of bulk metallic glass and its crystalline alloy is characterized by 18O 2 isotopic tracer. In the oxidation, the promotion of m-ZrO 2 on the crystalline substrate is attributed to the inward diffusion of oxygen.

KW - B. Diffusion

KW - B. Glasses, metallic

KW - B. Oxidation

KW - F. Secondary ion mass spectrometry

UR - https://www.scopus.com/pages/publications/84867017599

U2 - 10.1016/j.intermet.2012.05.009

DO - 10.1016/j.intermet.2012.05.009

M3 - 文章

AN - SCOPUS:84867017599

SN - 0966-9795

VL - 31

SP - 21

EP - 25

JO - Intermetallics

JF - Intermetallics

ER -

The relationship between t-ZrO ₂ stability and the crystallization of a Zr-based bulk metallic glass during oxidation

Abstract

Keywords

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