Abstract
The lattice, magnetic and electronic transport properties of the compounds Mn3Sn1-xSixC (0<x<;0.4) are investigated. The results have shown that Si-doping in the antiperovskite Mn3SnC induces the decrease of the nearest neighbouring Mn-Mn bond distance of Mn3Sn1-xSixC, and the magnetic structure transforms from ferrimagnetic to antiferromagnetic when x>0.2. With the increase of Si, the Neel temperature TN rises. The TN of Mn3Sn1-xSixC(x=0.2, 0.3, 0.4) are 217 K, 257 K and 290 K, respectively. However, the magnetovolume effect is quenched. In Mn3SnC and Mn3Sn1-xSixC (x=0.2, 0.3, 0.4) compounds, there exists an anomalous increase in resistivity at a certain temperature that coincides well with their Curie temperature TC or Neel temperature TN. The temperature dependence of the resistivity of Mn3Sn1-xSixC (x=0, 0.2, 0.3, 0.4) exhibits semiconducting-like behavior at low temperature and metallic-like behavior at high temperature.
| Original language | English |
|---|---|
| Pages (from-to) | 22-25 |
| Number of pages | 4 |
| Journal | Journal of Magnetism and Magnetic Materials |
| Volume | 391 |
| DOIs | |
| State | Published - 1 Oct 2015 |
Keywords
- Antiperovskite structure
- Electronic transport
- MnSnSiC
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