The magnetism and electronic transport properties of Mn3Sn1-xSixC

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Abstract

The lattice, magnetic and electronic transport properties of the compounds Mn3Sn1-xSixC (0<x<;0.4) are investigated. The results have shown that Si-doping in the antiperovskite Mn3SnC induces the decrease of the nearest neighbouring Mn-Mn bond distance of Mn3Sn1-xSixC, and the magnetic structure transforms from ferrimagnetic to antiferromagnetic when x>0.2. With the increase of Si, the Neel temperature TN rises. The TN of Mn3Sn1-xSixC(x=0.2, 0.3, 0.4) are 217 K, 257 K and 290 K, respectively. However, the magnetovolume effect is quenched. In Mn3SnC and Mn3Sn1-xSixC (x=0.2, 0.3, 0.4) compounds, there exists an anomalous increase in resistivity at a certain temperature that coincides well with their Curie temperature TC or Neel temperature TN. The temperature dependence of the resistivity of Mn3Sn1-xSixC (x=0, 0.2, 0.3, 0.4) exhibits semiconducting-like behavior at low temperature and metallic-like behavior at high temperature.

Original languageEnglish
Pages (from-to)22-25
Number of pages4
JournalJournal of Magnetism and Magnetic Materials
Volume391
DOIs
StatePublished - 1 Oct 2015

Keywords

  • Antiperovskite structure
  • Electronic transport
  • MnSnSiC

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