The combined effect of chemical and structural factors on pitting corrosion induced by MnS-(Cr, Mn, Al)O duplex inclusions

In situ atomic force microscopy, scanning Kelvin probe force microscopy, and potential pulse technology were used to study the pitting behavior induced by inclusions in AM355 martensitic stainless steel. The MnS-(Cr, Mn, Al)O duplex inclusion exhibited the highest sensitivity to the pitting corrosion with respect to the individual MnS and (Cr, Mn, Al)O inclusions. When exposed to a solution containing Cl⁻, the selective dissolution occurred on the sulfide segment of the duplex inclusion, leading to trenching along the oxide part. The dissolution mechanism of MnS segment in the duplex inclusion is similar to the individual MnS inclusion. The Cr depletion in the boundary layer at the inclusion/metal interface promoted the transition from metastable to stable pitting corrosion in the duplex inclusion.