TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

Teng Wang; Ning Jiao

doi:10.1021/ja403824y

TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

Teng Wang
, Ning Jiao^*

^*Corresponding author for this work

Peking University
Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

238 Scopus citations

Abstract

A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

Original language	English
Pages (from-to)	11692-11695
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	32
DOIs	https://doi.org/10.1021/ja403824y
State	Published - 14 Aug 2013
Externally published	Yes

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title = "TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage",

abstract = "A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.",

author = "Teng Wang and Ning Jiao",

year = "2013",

month = aug,

day = "14",

doi = "10.1021/ja403824y",

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T1 - TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

AU - Wang, Teng

AU - Jiao, Ning

PY - 2013/8/14

Y1 - 2013/8/14

N2 - A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

AB - A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

UR - https://www.scopus.com/pages/publications/84882276526

U2 - 10.1021/ja403824y

DO - 10.1021/ja403824y

M3 - 文章

C2 - 23902362

AN - SCOPUS:84882276526

SN - 0002-7863

VL - 135

SP - 11692

EP - 11695

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 32

ER -

TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

Abstract

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