Synthesis of silicone-acrylate copolymer latexes and their film properties

Chengyou Kan; Qing Yuan; Mingcun Wang; Xiangzheng Kong

doi:10.1002/(SICI)1099-1581(199602)7:2<95::AID-PAT450>3.0.CO;2-4

Synthesis of silicone-acrylate copolymer latexes and their film properties

Chengyou Kan
, Qing Yuan
, Mingcun Wang
, Xiangzheng Kong^*

^*Corresponding author for this work

Shandong University

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Emulsion copolymerization of silicones (octomethyl tetracyclosiloxane, D₄ and methacryloxypropyl trimethoxy silane, MATS) and acrylics was carried out using three different polymerization processes: semicontinuous monomer emulsion addition, batch and initiator solution addition. Results showed that only the semicontinuous process led to a stable latex with monodisperse particles. Various polymerizations were carried out through this process with varying silicone/acrylic ratios and MATS content. Films were obtained from different latexes: their properties are significantly influenced by silicone and MATS contents in copolymers.

Original language	English
Pages (from-to)	95-97
Number of pages	3
Journal	Polymers for Advanced Technologies
Volume	7
Issue number	2
DOIs	https://doi.org/10.1002/(SICI)1099-1581(199602)7:2<95::AID-PAT450>3.0.CO;2-4
State	Published - Feb 1996
Externally published	Yes

Keywords

Emulsion copolymerization
Film properties
Polymerization process
Silicone-acrylate copolymer
Siloxanes

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10.1002/(SICI)1099-1581(199602)7:2<95::AID-PAT450>3.0.CO;2-4

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title = "Synthesis of silicone-acrylate copolymer latexes and their film properties",

abstract = "Emulsion copolymerization of silicones (octomethyl tetracyclosiloxane, D4 and methacryloxypropyl trimethoxy silane, MATS) and acrylics was carried out using three different polymerization processes: semicontinuous monomer emulsion addition, batch and initiator solution addition. Results showed that only the semicontinuous process led to a stable latex with monodisperse particles. Various polymerizations were carried out through this process with varying silicone/acrylic ratios and MATS content. Films were obtained from different latexes: their properties are significantly influenced by silicone and MATS contents in copolymers.",

keywords = "Emulsion copolymerization, Film properties, Polymerization process, Silicone-acrylate copolymer, Siloxanes",

author = "Chengyou Kan and Qing Yuan and Mingcun Wang and Xiangzheng Kong",

year = "1996",

month = feb,

doi = "10.1002/(SICI)1099-1581(199602)7:2<95::AID-PAT450>3.0.CO;2-4",

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journal = "Polymers for Advanced Technologies",

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T1 - Synthesis of silicone-acrylate copolymer latexes and their film properties

AU - Kan, Chengyou

AU - Yuan, Qing

AU - Wang, Mingcun

AU - Kong, Xiangzheng

PY - 1996/2

Y1 - 1996/2

N2 - Emulsion copolymerization of silicones (octomethyl tetracyclosiloxane, D4 and methacryloxypropyl trimethoxy silane, MATS) and acrylics was carried out using three different polymerization processes: semicontinuous monomer emulsion addition, batch and initiator solution addition. Results showed that only the semicontinuous process led to a stable latex with monodisperse particles. Various polymerizations were carried out through this process with varying silicone/acrylic ratios and MATS content. Films were obtained from different latexes: their properties are significantly influenced by silicone and MATS contents in copolymers.

AB - Emulsion copolymerization of silicones (octomethyl tetracyclosiloxane, D4 and methacryloxypropyl trimethoxy silane, MATS) and acrylics was carried out using three different polymerization processes: semicontinuous monomer emulsion addition, batch and initiator solution addition. Results showed that only the semicontinuous process led to a stable latex with monodisperse particles. Various polymerizations were carried out through this process with varying silicone/acrylic ratios and MATS content. Films were obtained from different latexes: their properties are significantly influenced by silicone and MATS contents in copolymers.

KW - Emulsion copolymerization

KW - Film properties

KW - Polymerization process

KW - Silicone-acrylate copolymer

KW - Siloxanes

UR - https://www.scopus.com/pages/publications/0030083920

U2 - 10.1002/(SICI)1099-1581(199602)7:2<95::AID-PAT450>3.0.CO;2-4

DO - 10.1002/(SICI)1099-1581(199602)7:2<95::AID-PAT450>3.0.CO;2-4

M3 - 文章

AN - SCOPUS:0030083920

SN - 1042-7147

VL - 7

SP - 95

EP - 97

JO - Polymers for Advanced Technologies

JF - Polymers for Advanced Technologies

IS - 2

ER -

Synthesis of silicone-acrylate copolymer latexes and their film properties

Abstract

Keywords

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