Synthesis of 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride and its easy degradation research

Juan Zhao; Shan Chen; Pengcheng Huang; Gong Chen

doi:10.1016/j.inoche.2011.03.035

Synthesis of 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride and its easy degradation research

Juan Zhao
, Shan Chen
, Pengcheng Huang
, Gong Chen^*

^*Corresponding author for this work

School of Materials Science and Engineering

Beihang University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

bis-C(cage)-substituted 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride was obtained from the reaction of 1,2-bis(phthalimidomethyl)-1,2- dicarba-closo-dodecaborane with sodium borohydride, followed by acid hydrolysis with glacial acetic acid. When the compound dissolved in DMSO, the easy degradation from the closo-stucture compound to corresponding nido-carborane derivative at room temperature occured.

Original language	English
Pages (from-to)	934-936
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2011.03.035
State	Published - Jun 2011

Keywords

BNCT
Bis-aminomethyl
Degradation
Dicarbadodecaborane

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10.1016/j.inoche.2011.03.035

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title = "Synthesis of 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride and its easy degradation research",

abstract = "bis-C(cage)-substituted 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride was obtained from the reaction of 1,2-bis(phthalimidomethyl)-1,2- dicarba-closo-dodecaborane with sodium borohydride, followed by acid hydrolysis with glacial acetic acid. When the compound dissolved in DMSO, the easy degradation from the closo-stucture compound to corresponding nido-carborane derivative at room temperature occured.",

keywords = "BNCT, Bis-aminomethyl, Degradation, Dicarbadodecaborane",

author = "Juan Zhao and Shan Chen and Pengcheng Huang and Gong Chen",

year = "2011",

month = jun,

doi = "10.1016/j.inoche.2011.03.035",

language = "英语",

volume = "14",

pages = "934--936",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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TY - JOUR

T1 - Synthesis of 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride and its easy degradation research

AU - Zhao, Juan

AU - Chen, Shan

AU - Huang, Pengcheng

AU - Chen, Gong

PY - 2011/6

Y1 - 2011/6

N2 - bis-C(cage)-substituted 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride was obtained from the reaction of 1,2-bis(phthalimidomethyl)-1,2- dicarba-closo-dodecaborane with sodium borohydride, followed by acid hydrolysis with glacial acetic acid. When the compound dissolved in DMSO, the easy degradation from the closo-stucture compound to corresponding nido-carborane derivative at room temperature occured.

AB - bis-C(cage)-substituted 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride was obtained from the reaction of 1,2-bis(phthalimidomethyl)-1,2- dicarba-closo-dodecaborane with sodium borohydride, followed by acid hydrolysis with glacial acetic acid. When the compound dissolved in DMSO, the easy degradation from the closo-stucture compound to corresponding nido-carborane derivative at room temperature occured.

KW - BNCT

KW - Bis-aminomethyl

KW - Degradation

KW - Dicarbadodecaborane

UR - https://www.scopus.com/pages/publications/79955823907

U2 - 10.1016/j.inoche.2011.03.035

DO - 10.1016/j.inoche.2011.03.035

M3 - 文章

AN - SCOPUS:79955823907

SN - 1387-7003

VL - 14

SP - 934

EP - 936

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Synthesis of 1,2-bis(aminomethyl)-1,2-dicarba-closo-dedocaborane hydrochloride and its easy degradation research

Abstract

Keywords

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