Synthesis and characterization of (Ce0.67Tb0.33)MnxMg1-xAl11 O19 phosphors derived by sol-gel processing

Junying Zhang; Zhongtai Zhang; Zilong Tang; Yuanhua Lin

doi:10.1111/j.1151-2916.2002.tb00208.x

Synthesis and characterization of (Ce_0.67Tb_0.33)Mn_xMg_1-xAl₁₁O₁₉ phosphors derived by sol-gel processing

Junying Zhang^*
, Zhongtai Zhang
, Zilong Tang
, Yuanhua Lin

^*Corresponding author for this work

Tsinghua University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A (Ce_0.67Tb_0.33)Mn_xMg_1-xAl₁₁O₁₉ phosphor powder was synthesized, using a simple sol-gel process, by mixing citric acid with CeO₂, Tb₄O₇, Al(NO₃)₃·9H₂O, Mg(OH)₂·4MgCO₃·6H₂O, and Mn(CH₃COO)₂. The phosphor crystallized completely at 1200°C, and the phosphor particle size was between 1 and 5 μm. The excitation spectrum was characteristic of Ce³⁺, while the emission spectrum was composed of lines from Tb³⁺ and Mn²⁺. The Mn²⁺ gave a green fluorescence band, and concentration quenching occurred when x > 0.10. The luminescent properties of the phosphor were explained by a configurational coordinate model.

Original language	English
Pages (from-to)	998-1000
Number of pages	3
Journal	Journal of the American Ceramic Society
Volume	85
Issue number	4
DOIs	https://doi.org/10.1111/j.1151-2916.2002.tb00208.x
State	Published - Apr 2002
Externally published	Yes

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@article{a25ed4dd3899425abdcc06a82e377daa,

title = "Synthesis and characterization of (Ce0.67Tb0.33)MnxMg1-xAl11 O19 phosphors derived by sol-gel processing",

abstract = "A (Ce0.67Tb0.33)MnxMg1-xAl11 O19 phosphor powder was synthesized, using a simple sol-gel process, by mixing citric acid with CeO2, Tb4O7, Al(NO3)3·9H2O, Mg(OH)2·4MgCO3·6H2O, and Mn(CH3COO)2. The phosphor crystallized completely at 1200°C, and the phosphor particle size was between 1 and 5 μm. The excitation spectrum was characteristic of Ce3+, while the emission spectrum was composed of lines from Tb3+ and Mn2+. The Mn2+ gave a green fluorescence band, and concentration quenching occurred when x > 0.10. The luminescent properties of the phosphor were explained by a configurational coordinate model.",

author = "Junying Zhang and Zhongtai Zhang and Zilong Tang and Yuanhua Lin",

year = "2002",

month = apr,

doi = "10.1111/j.1151-2916.2002.tb00208.x",

language = "英语",

volume = "85",

pages = "998--1000",

journal = "Journal of the American Ceramic Society",

issn = "0002-7820",

publisher = "Wiley-Blackwell",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterization of (Ce0.67Tb0.33)MnxMg1-xAl11 O19 phosphors derived by sol-gel processing

AU - Zhang, Junying

AU - Zhang, Zhongtai

AU - Tang, Zilong

AU - Lin, Yuanhua

PY - 2002/4

Y1 - 2002/4

N2 - A (Ce0.67Tb0.33)MnxMg1-xAl11 O19 phosphor powder was synthesized, using a simple sol-gel process, by mixing citric acid with CeO2, Tb4O7, Al(NO3)3·9H2O, Mg(OH)2·4MgCO3·6H2O, and Mn(CH3COO)2. The phosphor crystallized completely at 1200°C, and the phosphor particle size was between 1 and 5 μm. The excitation spectrum was characteristic of Ce3+, while the emission spectrum was composed of lines from Tb3+ and Mn2+. The Mn2+ gave a green fluorescence band, and concentration quenching occurred when x > 0.10. The luminescent properties of the phosphor were explained by a configurational coordinate model.

AB - A (Ce0.67Tb0.33)MnxMg1-xAl11 O19 phosphor powder was synthesized, using a simple sol-gel process, by mixing citric acid with CeO2, Tb4O7, Al(NO3)3·9H2O, Mg(OH)2·4MgCO3·6H2O, and Mn(CH3COO)2. The phosphor crystallized completely at 1200°C, and the phosphor particle size was between 1 and 5 μm. The excitation spectrum was characteristic of Ce3+, while the emission spectrum was composed of lines from Tb3+ and Mn2+. The Mn2+ gave a green fluorescence band, and concentration quenching occurred when x > 0.10. The luminescent properties of the phosphor were explained by a configurational coordinate model.

UR - https://www.scopus.com/pages/publications/0036544933

U2 - 10.1111/j.1151-2916.2002.tb00208.x

DO - 10.1111/j.1151-2916.2002.tb00208.x

M3 - 文章

AN - SCOPUS:0036544933

SN - 0002-7820

VL - 85

SP - 998

EP - 1000

JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

IS - 4

ER -

Synthesis and characterization of (Ce_0.67Tb_0.33)Mn_xMg_1-xAl₁₁O₁₉ phosphors derived by sol-gel processing

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