SU-79: a novel germanate with 3D 10- and 11-ring channels templated by a square-planar nickel complex

Shiliang Huang; Jie Su; Kirsten Christensen; A. Ken Inge; Jie Liang; Xiaodong Zou; Junliang Sun

doi:10.1039/c3qi00088e

SU-79: a novel germanate with 3D 10- and 11-ring channels templated by a square-planar nickel complex

Shiliang Huang
, Jie Su^*
, Kirsten Christensen
, A. Ken Inge
, Jie Liang
, Xiaodong Zou
, Junliang Sun

^*Corresponding author for this work

Stockholm University
China Academy of Engineering Physics
Diamond Light Source
Kiel University
Peking University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

An open-framework germanate denoted as SU-79 with the chemical formula [Ge_12.5O₂₆(OH)₂][Ni(C₃N₂H₁₀)₂]_1.1(NH₄)_0.8(C₃N₂H₁₂)_0.5(C₃N₂H₁₀)_1.5(H₂O)₂ has been synthesized under hydro/solvothermal conditions using [Ni(1,2-pda)₂]²⁺ (1,2-pda = 1,2-diaminopropane) and 1,2-pda as templates. Owing to the complicated pseudo-merohedral twinning in the crystals, the rotation electron diffraction (RED) method was used for the unit cell and space group determination. The structure of SU-79 was solved and refined based on synchrotron single crystal X-ray diffraction data. SU-79 exhibits a 3D open germanate framework built with Ge₁₃ clusters, consisting of a 3D channel system with interconnected 10- and 11-ring channels. Interestingly, helical GeO₄ tetrahedral chains with left-handed/right-handed chirality were found in the structure. The [Ni(1,2-pda)₂]²⁺ complexes, adopting in a square-planar geometry, show a structure directing role on the SU-79 framework via hydrogen bonds. Comparing with its related structure, SU-67, the formation of the pseudo-merohedric twinning in SU-79 was also discussed.

Original language	English
Pages (from-to)	278-283
Number of pages	6
Journal	Inorganic Chemistry Frontiers
Volume	1
Issue number	3
DOIs	https://doi.org/10.1039/c3qi00088e
State	Published - 1 Mar 2014
Externally published	Yes

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title = "SU-79: a novel germanate with 3D 10- and 11-ring channels templated by a square-planar nickel complex",

abstract = "An open-framework germanate denoted as SU-79 with the chemical formula [Ge12.5O26(OH)2][Ni(C3N2H10)2]1.1(NH4)0.8(C3N2H12)0.5(C3N2H10)1.5(H2O)2 has been synthesized under hydro/solvothermal conditions using [Ni(1,2-pda)2]2+ (1,2-pda = 1,2-diaminopropane) and 1,2-pda as templates. Owing to the complicated pseudo-merohedral twinning in the crystals, the rotation electron diffraction (RED) method was used for the unit cell and space group determination. The structure of SU-79 was solved and refined based on synchrotron single crystal X-ray diffraction data. SU-79 exhibits a 3D open germanate framework built with Ge13 clusters, consisting of a 3D channel system with interconnected 10- and 11-ring channels. Interestingly, helical GeO4 tetrahedral chains with left-handed/right-handed chirality were found in the structure. The [Ni(1,2-pda)2]2+ complexes, adopting in a square-planar geometry, show a structure directing role on the SU-79 framework via hydrogen bonds. Comparing with its related structure, SU-67, the formation of the pseudo-merohedric twinning in SU-79 was also discussed.",

author = "Shiliang Huang and Jie Su and Kirsten Christensen and Inge, \{A. Ken\} and Jie Liang and Xiaodong Zou and Junliang Sun",

note = "Publisher Copyright: This journal is {\textcopyright} the Partner Organisations 2014.",

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doi = "10.1039/c3qi00088e",

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T2 - a novel germanate with 3D 10- and 11-ring channels templated by a square-planar nickel complex

AU - Huang, Shiliang

AU - Su, Jie

AU - Christensen, Kirsten

AU - Inge, A. Ken

AU - Liang, Jie

AU - Zou, Xiaodong

AU - Sun, Junliang

PY - 2014/3/1

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N2 - An open-framework germanate denoted as SU-79 with the chemical formula [Ge12.5O26(OH)2][Ni(C3N2H10)2]1.1(NH4)0.8(C3N2H12)0.5(C3N2H10)1.5(H2O)2 has been synthesized under hydro/solvothermal conditions using [Ni(1,2-pda)2]2+ (1,2-pda = 1,2-diaminopropane) and 1,2-pda as templates. Owing to the complicated pseudo-merohedral twinning in the crystals, the rotation electron diffraction (RED) method was used for the unit cell and space group determination. The structure of SU-79 was solved and refined based on synchrotron single crystal X-ray diffraction data. SU-79 exhibits a 3D open germanate framework built with Ge13 clusters, consisting of a 3D channel system with interconnected 10- and 11-ring channels. Interestingly, helical GeO4 tetrahedral chains with left-handed/right-handed chirality were found in the structure. The [Ni(1,2-pda)2]2+ complexes, adopting in a square-planar geometry, show a structure directing role on the SU-79 framework via hydrogen bonds. Comparing with its related structure, SU-67, the formation of the pseudo-merohedric twinning in SU-79 was also discussed.

AB - An open-framework germanate denoted as SU-79 with the chemical formula [Ge12.5O26(OH)2][Ni(C3N2H10)2]1.1(NH4)0.8(C3N2H12)0.5(C3N2H10)1.5(H2O)2 has been synthesized under hydro/solvothermal conditions using [Ni(1,2-pda)2]2+ (1,2-pda = 1,2-diaminopropane) and 1,2-pda as templates. Owing to the complicated pseudo-merohedral twinning in the crystals, the rotation electron diffraction (RED) method was used for the unit cell and space group determination. The structure of SU-79 was solved and refined based on synchrotron single crystal X-ray diffraction data. SU-79 exhibits a 3D open germanate framework built with Ge13 clusters, consisting of a 3D channel system with interconnected 10- and 11-ring channels. Interestingly, helical GeO4 tetrahedral chains with left-handed/right-handed chirality were found in the structure. The [Ni(1,2-pda)2]2+ complexes, adopting in a square-planar geometry, show a structure directing role on the SU-79 framework via hydrogen bonds. Comparing with its related structure, SU-67, the formation of the pseudo-merohedric twinning in SU-79 was also discussed.

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U2 - 10.1039/c3qi00088e

DO - 10.1039/c3qi00088e

M3 - 文章

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JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 3

ER -

SU-79: a novel germanate with 3D 10- and 11-ring channels templated by a square-planar nickel complex

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