Study of lithiated Nafion ionomer for lithium batteries

H. Y. Liang; X. P. Qiu; S. C. Zhang; W. T. Zhu; L. Q. Chen

doi:10.1007/s10800-004-1767-0

Study of lithiated Nafion ionomer for lithium batteries

H. Y. Liang
, X. P. Qiu^*
, S. C. Zhang
, W. T. Zhu
, L. Q. Chen

^*Corresponding author for this work

School of Materials Science and Engineering

Tsinghua University

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

Lithiated Nafion 112 ionomer was characterized by FT-IR spectroscopy, AC impedance, and cyclic voltammetry. The ionomer swollen with mixed solvents of propylene carbonate (PC) and ethylene carbonate shows ionic conductivity of 8.18 × 10^-5 S cm^-1 at 25°C and good electrochemical stability to allow operation in Li/ionomer/ LiCoO₂ cells. The discharge capacity of the first cycle is 126 mAh g^-1. Significant capacity loss occurs during cycling due to the presence of PC. AC impedance shows that the passive layer formed at the Li/ionomer interface dominates the cycling performance of the cell.

Original language	English
Pages (from-to)	1211-1214
Number of pages	4
Journal	Journal of Applied Electrochemistry
Volume	34
Issue number	12
DOIs	https://doi.org/10.1007/s10800-004-1767-0
State	Published - Dec 2004

Keywords

Ionomer
Lithium batteries
Nafion membrane
Polymer electrolyte

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title = "Study of lithiated Nafion ionomer for lithium batteries",

abstract = "Lithiated Nafion 112 ionomer was characterized by FT-IR spectroscopy, AC impedance, and cyclic voltammetry. The ionomer swollen with mixed solvents of propylene carbonate (PC) and ethylene carbonate shows ionic conductivity of 8.18 × 10-5 S cm-1 at 25°C and good electrochemical stability to allow operation in Li/ionomer/ LiCoO2 cells. The discharge capacity of the first cycle is 126 mAh g-1. Significant capacity loss occurs during cycling due to the presence of PC. AC impedance shows that the passive layer formed at the Li/ionomer interface dominates the cycling performance of the cell.",

keywords = "Ionomer, Lithium batteries, Nafion membrane, Polymer electrolyte",

author = "Liang, \{H. Y.\} and Qiu, \{X. P.\} and Zhang, \{S. C.\} and Zhu, \{W. T.\} and Chen, \{L. Q.\}",

year = "2004",

month = dec,

doi = "10.1007/s10800-004-1767-0",

language = "英语",

volume = "34",

pages = "1211--1214",

journal = "Journal of Applied Electrochemistry",

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T1 - Study of lithiated Nafion ionomer for lithium batteries

AU - Liang, H. Y.

AU - Qiu, X. P.

AU - Zhang, S. C.

AU - Zhu, W. T.

AU - Chen, L. Q.

PY - 2004/12

Y1 - 2004/12

N2 - Lithiated Nafion 112 ionomer was characterized by FT-IR spectroscopy, AC impedance, and cyclic voltammetry. The ionomer swollen with mixed solvents of propylene carbonate (PC) and ethylene carbonate shows ionic conductivity of 8.18 × 10-5 S cm-1 at 25°C and good electrochemical stability to allow operation in Li/ionomer/ LiCoO2 cells. The discharge capacity of the first cycle is 126 mAh g-1. Significant capacity loss occurs during cycling due to the presence of PC. AC impedance shows that the passive layer formed at the Li/ionomer interface dominates the cycling performance of the cell.

AB - Lithiated Nafion 112 ionomer was characterized by FT-IR spectroscopy, AC impedance, and cyclic voltammetry. The ionomer swollen with mixed solvents of propylene carbonate (PC) and ethylene carbonate shows ionic conductivity of 8.18 × 10-5 S cm-1 at 25°C and good electrochemical stability to allow operation in Li/ionomer/ LiCoO2 cells. The discharge capacity of the first cycle is 126 mAh g-1. Significant capacity loss occurs during cycling due to the presence of PC. AC impedance shows that the passive layer formed at the Li/ionomer interface dominates the cycling performance of the cell.

KW - Ionomer

KW - Lithium batteries

KW - Nafion membrane

KW - Polymer electrolyte

UR - https://www.scopus.com/pages/publications/10844250934

U2 - 10.1007/s10800-004-1767-0

DO - 10.1007/s10800-004-1767-0

M3 - 文章

AN - SCOPUS:10844250934

SN - 0021-891X

VL - 34

SP - 1211

EP - 1214

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 12

ER -

Study of lithiated Nafion ionomer for lithium batteries

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