Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines

Jingjing Wang; Yuran Qin; Ke Cui; Xueqi Li; Mingyue Cui; Sheng Cao; Linbo Zhang; Qin Shen; Teng Wang; Feng Li

doi:10.1039/d4cc05675b

Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines

Jingjing Wang
, Yuran Qin
, Ke Cui
, Xueqi Li
, Mingyue Cui
, Sheng Cao
, Linbo Zhang
, Qin Shen
, Teng Wang^*
, Feng Li^*

^*Corresponding author for this work

Zaozhuang University
Zhejiang University
Beijing University of Chemical Technology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A silver-catalyzed cross coupling of cyclic aldimines and α-imino-oxy acids has been developed. The solvent-dependent reaction could selectively deliver either cyclic imine moiety retained nitriles or ring-opened oxonitriles in moderate yields. The mechanistic studies show that the reaction undergoes a radical pathway.

Original language	English
Pages (from-to)	3359-3362
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	16
DOIs	https://doi.org/10.1039/d4cc05675b
State	Published - 23 Jan 2025
Externally published	Yes

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10.1039/d4cc05675b

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title = "Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines",

abstract = "A silver-catalyzed cross coupling of cyclic aldimines and α-imino-oxy acids has been developed. The solvent-dependent reaction could selectively deliver either cyclic imine moiety retained nitriles or ring-opened oxonitriles in moderate yields. The mechanistic studies show that the reaction undergoes a radical pathway.",

author = "Jingjing Wang and Yuran Qin and Ke Cui and Xueqi Li and Mingyue Cui and Sheng Cao and Linbo Zhang and Qin Shen and Teng Wang and Feng Li",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

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doi = "10.1039/d4cc05675b",

language = "英语",

volume = "61",

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T1 - Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines

AU - Wang, Jingjing

AU - Qin, Yuran

AU - Cui, Ke

AU - Li, Xueqi

AU - Cui, Mingyue

AU - Cao, Sheng

AU - Zhang, Linbo

AU - Shen, Qin

AU - Wang, Teng

AU - Li, Feng

PY - 2025/1/23

Y1 - 2025/1/23

N2 - A silver-catalyzed cross coupling of cyclic aldimines and α-imino-oxy acids has been developed. The solvent-dependent reaction could selectively deliver either cyclic imine moiety retained nitriles or ring-opened oxonitriles in moderate yields. The mechanistic studies show that the reaction undergoes a radical pathway.

AB - A silver-catalyzed cross coupling of cyclic aldimines and α-imino-oxy acids has been developed. The solvent-dependent reaction could selectively deliver either cyclic imine moiety retained nitriles or ring-opened oxonitriles in moderate yields. The mechanistic studies show that the reaction undergoes a radical pathway.

UR - https://www.scopus.com/pages/publications/85216719393

U2 - 10.1039/d4cc05675b

DO - 10.1039/d4cc05675b

M3 - 文章

C2 - 39882770

AN - SCOPUS:85216719393

SN - 1359-7345

VL - 61

SP - 3359

EP - 3362

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines

Abstract

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