Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Tao Shen; Teng Wang; Chong Qin; Ning Jiao

doi:10.1002/anie.201300193

Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Tao Shen
, Teng Wang
, Chong Qin
, Ning Jiao^*

^*Corresponding author for this work

Peking University
Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

170 Scopus citations

Abstract

Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.

Original language	English
Pages (from-to)	6677-6680
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	26
DOIs	https://doi.org/10.1002/anie.201300193
State	Published - 24 Jun 2013
Externally published	Yes

Keywords

alkynes
azides
nitriles
rearrangement
silver

Access to Document

10.1002/anie.201300193

Cite this

@article{13d5b31bdc8d4d94b4fe97b3762b0275,

title = "Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage",

abstract = "Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.",

keywords = "alkynes, azides, nitriles, rearrangement, silver",

author = "Tao Shen and Teng Wang and Chong Qin and Ning Jiao",

year = "2013",

month = jun,

day = "24",

doi = "10.1002/anie.201300193",

language = "英语",

volume = "52",

pages = "6677--6680",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "26",

}

TY - JOUR

T1 - Silver-catalyzed nitrogenation of alkynes

T2 - A direct approach to nitriles through C≡C bond cleavage

AU - Shen, Tao

AU - Wang, Teng

AU - Qin, Chong

AU - Jiao, Ning

PY - 2013/6/24

Y1 - 2013/6/24

N2 - Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.

AB - Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.

KW - alkynes

KW - azides

KW - nitriles

KW - rearrangement

KW - silver

UR - https://www.scopus.com/pages/publications/84879351373

U2 - 10.1002/anie.201300193

DO - 10.1002/anie.201300193

M3 - 文章

C2 - 23554282

AN - SCOPUS:84879351373

SN - 1433-7851

VL - 52

SP - 6677

EP - 6680

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 26

ER -

Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this