Self-assembly of near-unity helical Ce1-: XMxO2 (x = 0.1, M = Ni and Bi) solid solutions with tunable optical activity

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Abstract

Left-handed Ni/Bi modified Ce1-xMxO2 solid solutions were synthesized via a self-assembly process. The solutions show tunable optical activity throughout the whole UV-visible range. The negative Cotton effect observed in the UV-visible range is ascribed to the electronic exciton coupling between left-handed helical structures.

Original languageEnglish
Pages (from-to)1577-1580
Number of pages4
JournalNew Journal of Chemistry
Volume42
Issue number3
DOIs
StatePublished - 2018

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