Reassessing host selection in Cl-rich argyrodite electrolytes: the stability–conductivity trade-off under industrial dry-room conditions

Shaoyu Mo; Zunqiu Xiao; Dongcheng Lin; Maxwell Aaron Wallace; Wei Wei; Keming Yan; Kejia Xiang; Huaying Wang; Tao Ye; Huixian Jiang; Shitong Wang; Zilong Tang

doi:10.1039/d6cc01822j

Reassessing host selection in Cl-rich argyrodite electrolytes: the stability–conductivity trade-off under industrial dry-room conditions

Shaoyu Mo
, Zunqiu Xiao^*
, Dongcheng Lin^*
, Maxwell Aaron Wallace
, Wei Wei
, Keming Yan
, Kejia Xiang
, Huaying Wang
, Tao Ye
, Huixian Jiang
, Shitong Wang^*
, Zilong Tang^*

^*Corresponding author for this work

School of Physics

Tsinghua University
China Automotive Battery Research Institute Co., Ltd

Research output: Contribution to journal › Article › peer-review

Abstract

Under simulated industrial dry-room conditions, Cl-rich argyrodite Li_5.4PS_4.4Cl_1.6 better preserves its structure, Li-ion transport, electronic insulation and cell performance than the high-conductivity Li_5.5PS_4.5Cl_1.5, owing to a pre-existing amorphous LiCl surface layer. These results refine host selection criteria for Cl-rich argyrodite electrolytes.

Original language	English
Pages (from-to)	12397-12401
Number of pages	5
Journal	Chemical Communications
Volume	62
Issue number	49
DOIs	https://doi.org/10.1039/d6cc01822j
State	Published - 25 Jun 2026

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10.1039/d6cc01822j

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title = "Reassessing host selection in Cl-rich argyrodite electrolytes: the stability–conductivity trade-off under industrial dry-room conditions",

abstract = "Under simulated industrial dry-room conditions, Cl-rich argyrodite Li5.4PS4.4Cl1.6 better preserves its structure, Li-ion transport, electronic insulation and cell performance than the high-conductivity Li5.5PS4.5Cl1.5, owing to a pre-existing amorphous LiCl surface layer. These results refine host selection criteria for Cl-rich argyrodite electrolytes.",

author = "Shaoyu Mo and Zunqiu Xiao and Dongcheng Lin and Wallace, \{Maxwell Aaron\} and Wei Wei and Keming Yan and Kejia Xiang and Huaying Wang and Tao Ye and Huixian Jiang and Shitong Wang and Zilong Tang",

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year = "2026",

month = jun,

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doi = "10.1039/d6cc01822j",

language = "英语",

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TY - JOUR

T1 - Reassessing host selection in Cl-rich argyrodite electrolytes

T2 - the stability–conductivity trade-off under industrial dry-room conditions

AU - Mo, Shaoyu

AU - Xiao, Zunqiu

AU - Lin, Dongcheng

AU - Wallace, Maxwell Aaron

AU - Wei, Wei

AU - Yan, Keming

AU - Xiang, Kejia

AU - Wang, Huaying

AU - Ye, Tao

AU - Jiang, Huixian

AU - Wang, Shitong

AU - Tang, Zilong

PY - 2026/6/25

Y1 - 2026/6/25

N2 - Under simulated industrial dry-room conditions, Cl-rich argyrodite Li5.4PS4.4Cl1.6 better preserves its structure, Li-ion transport, electronic insulation and cell performance than the high-conductivity Li5.5PS4.5Cl1.5, owing to a pre-existing amorphous LiCl surface layer. These results refine host selection criteria for Cl-rich argyrodite electrolytes.

AB - Under simulated industrial dry-room conditions, Cl-rich argyrodite Li5.4PS4.4Cl1.6 better preserves its structure, Li-ion transport, electronic insulation and cell performance than the high-conductivity Li5.5PS4.5Cl1.5, owing to a pre-existing amorphous LiCl surface layer. These results refine host selection criteria for Cl-rich argyrodite electrolytes.

UR - https://www.scopus.com/pages/publications/105041294210

U2 - 10.1039/d6cc01822j

DO - 10.1039/d6cc01822j

M3 - 文章

AN - SCOPUS:105041294210

SN - 1359-7345

VL - 62

SP - 12397

EP - 12401

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Reassessing host selection in Cl-rich argyrodite electrolytes: the stability–conductivity trade-off under industrial dry-room conditions

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