Preparation and performance of a composite polyimide/poly(vinylidene fluoride-co-hexafluoropropylene)/nano-Al2O3 polymer electrolyte for lithium-sulfur cell

Mumin Rao; Xiaogang Li; Youhao Liao; Xiaoping Li; Weishan Li

doi:10.1007/s11581-014-1360-4

Preparation and performance of a composite polyimide/poly(vinylidene fluoride-co-hexafluoropropylene)/nano-Al₂O₃ polymer electrolyte for lithium-sulfur cell

Mumin Rao
, Xiaogang Li
, Youhao Liao
, Xiaoping Li
, Weishan Li^*

^*Corresponding author for this work

South China Normal University
Ltd
South China University of Technology

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A novel gel polymer electrolyte (GPE) based on an electrospun polymer membrane of polyimide (PI) activating with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and further coating with nano-Al₂O₃ was prepared, and its performance for lithium-sulfur (Li-S) cell was investigated. It is found that the Li-S cell using the new GPE enabled achieving a stable discharge capacity of 820 mAh g⁻¹ after more than 100 cycles. This new GPE system with activating with PVDF-HFP and further coating with nano-Al₂O₃ was capable of upholding the electrolyte solution and can suppress the dissolution of the intermediate products generated during the discharge process and thus improves the performance of Li-S cell.

Original language	English
Pages (from-to)	1937-1943
Number of pages	7
Journal	Ionics
Volume	21
Issue number	7
DOIs	https://doi.org/10.1007/s11581-014-1360-4
State	Published - 25 Jul 2015
Externally published	Yes

Keywords

Gel polymer electrolyte
Lithium sulfur cell
Nano-AlO
Poly(vinylidene fluoride-co-hexafluoropropylene)
Polyimide

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10.1007/s11581-014-1360-4

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title = "Preparation and performance of a composite polyimide/poly(vinylidene fluoride-co-hexafluoropropylene)/nano-Al2O3 polymer electrolyte for lithium-sulfur cell",

abstract = "A novel gel polymer electrolyte (GPE) based on an electrospun polymer membrane of polyimide (PI) activating with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and further coating with nano-Al2O3 was prepared, and its performance for lithium-sulfur (Li-S) cell was investigated. It is found that the Li-S cell using the new GPE enabled achieving a stable discharge capacity of 820 mAh g−1 after more than 100 cycles. This new GPE system with activating with PVDF-HFP and further coating with nano-Al2O3 was capable of upholding the electrolyte solution and can suppress the dissolution of the intermediate products generated during the discharge process and thus improves the performance of Li-S cell.",

keywords = "Gel polymer electrolyte, Lithium sulfur cell, Nano-AlO, Poly(vinylidene fluoride-co-hexafluoropropylene), Polyimide",

author = "Mumin Rao and Xiaogang Li and Youhao Liao and Xiaoping Li and Weishan Li",

note = "Publisher Copyright: {\textcopyright} 2015, Springer-Verlag Berlin Heidelberg.",

year = "2015",

month = jul,

day = "25",

doi = "10.1007/s11581-014-1360-4",

language = "英语",

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pages = "1937--1943",

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issn = "0947-7047",

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TY - JOUR

T1 - Preparation and performance of a composite polyimide/poly(vinylidene fluoride-co-hexafluoropropylene)/nano-Al2O3 polymer electrolyte for lithium-sulfur cell

AU - Rao, Mumin

AU - Li, Xiaogang

AU - Liao, Youhao

AU - Li, Xiaoping

AU - Li, Weishan

PY - 2015/7/25

Y1 - 2015/7/25

N2 - A novel gel polymer electrolyte (GPE) based on an electrospun polymer membrane of polyimide (PI) activating with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and further coating with nano-Al2O3 was prepared, and its performance for lithium-sulfur (Li-S) cell was investigated. It is found that the Li-S cell using the new GPE enabled achieving a stable discharge capacity of 820 mAh g−1 after more than 100 cycles. This new GPE system with activating with PVDF-HFP and further coating with nano-Al2O3 was capable of upholding the electrolyte solution and can suppress the dissolution of the intermediate products generated during the discharge process and thus improves the performance of Li-S cell.

AB - A novel gel polymer electrolyte (GPE) based on an electrospun polymer membrane of polyimide (PI) activating with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and further coating with nano-Al2O3 was prepared, and its performance for lithium-sulfur (Li-S) cell was investigated. It is found that the Li-S cell using the new GPE enabled achieving a stable discharge capacity of 820 mAh g−1 after more than 100 cycles. This new GPE system with activating with PVDF-HFP and further coating with nano-Al2O3 was capable of upholding the electrolyte solution and can suppress the dissolution of the intermediate products generated during the discharge process and thus improves the performance of Li-S cell.

KW - Gel polymer electrolyte

KW - Lithium sulfur cell

KW - Nano-AlO

KW - Poly(vinylidene fluoride-co-hexafluoropropylene)

KW - Polyimide

UR - https://www.scopus.com/pages/publications/84931956674

U2 - 10.1007/s11581-014-1360-4

DO - 10.1007/s11581-014-1360-4

M3 - 文章

AN - SCOPUS:84931956674

SN - 0947-7047

VL - 21

SP - 1937

EP - 1943

JO - Ionics

JF - Ionics

IS - 7

ER -

Preparation and performance of a composite polyimide/poly(vinylidene fluoride-co-hexafluoropropylene)/nano-Al₂O₃ polymer electrolyte for lithium-sulfur cell

Abstract

Keywords

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