Abstract
The morphology, composition, and structure of precipitates in an Al-Si-Mg-Hf alloy after heat treatment at 560°C for 20 h were studied by means of C s-corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), energy dispersive X-ray spectrometry (EDS), high-resolution transmission electron microscopy (HRTEM), and first-principle calculations. Precipitates with three kinds of morphologies were observed. The rectangular and square precipitates were predominantly (Si2-xAlx)Hf phases, while the nanobelt-like precipitate is the Si2Hf phase. First-principle calculations were used to show that the Si6 and Si8 sites were the most favorable sites for Al incorporation in the orthorhombic Si2Hf phase.
| Original language | English |
|---|---|
| Pages (from-to) | 724-729 |
| Number of pages | 6 |
| Journal | Microscopy and Microanalysis |
| Volume | 23 |
| Issue number | 4 |
| DOIs | |
| State | Published - 1 Aug 2017 |
| Externally published | Yes |
Keywords
- HAADF-STEM
- Hf-containing precipitates
- aluminum alloys
- first-principle calculations
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