Polyrotaxane-Based Solid Polymer Electrolyte with a Macromolecular Crosslinker

Rui Dong Wang; Yi Fei Zhang; Xiao Long Han; Xiao Yang Fan; Jun Tian; Yu Kun Gao; Ting Ting You; Peng Gang Yin

doi:10.1021/acsapm.4c02670

Polyrotaxane-Based Solid Polymer Electrolyte with a Macromolecular Crosslinker

Rui Dong Wang
, Yi Fei Zhang
, Xiao Long Han
, Xiao Yang Fan
, Jun Tian
, Yu Kun Gao^*
, Ting Ting You^*
, Peng Gang Yin^*

^*Corresponding author for this work

School of Chemistry

Beihang University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

This study explores an approach to incorporating polyrotaxane into solid polymer electrolytes (SPEs) through crosslinking with poly(ethylene glycol) (PEG). By leveraging the unique properties of polyrotaxane and the flexibility of PEG, we have developed SPEs with enhanced ionic conductivity, mechanical strength, and thermal stability. Our results indicate that the SPE film, containing equal weights of hydroxypropyl polyrotaxane (HyPR) and PEG with a molecular weight of 10000 Da, exhibits high thermal resistance above 150 °C, impressive flexibility with an elongation at break exceeding 550%, and an ionic conductivity of 2.715 × 10^-5 S cm^-1 at 30 °C.

Original language	English
Pages (from-to)	15124-15135
Number of pages	12
Journal	ACS Applied Polymer Materials
Volume	6
Issue number	24
DOIs	https://doi.org/10.1021/acsapm.4c02670
State	Published - 27 Dec 2024

Keywords

cross-linking
high ionic conductivity
polyrotaxane
slide-ring
solid polymer electrolyte

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10.1021/acsapm.4c02670

Cite this

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title = "Polyrotaxane-Based Solid Polymer Electrolyte with a Macromolecular Crosslinker",

abstract = "This study explores an approach to incorporating polyrotaxane into solid polymer electrolytes (SPEs) through crosslinking with poly(ethylene glycol) (PEG). By leveraging the unique properties of polyrotaxane and the flexibility of PEG, we have developed SPEs with enhanced ionic conductivity, mechanical strength, and thermal stability. Our results indicate that the SPE film, containing equal weights of hydroxypropyl polyrotaxane (HyPR) and PEG with a molecular weight of 10000 Da, exhibits high thermal resistance above 150 °C, impressive flexibility with an elongation at break exceeding 550\%, and an ionic conductivity of 2.715 × 10-5 S cm-1 at 30 °C.",

keywords = "cross-linking, high ionic conductivity, polyrotaxane, slide-ring, solid polymer electrolyte",

author = "Wang, \{Rui Dong\} and Zhang, \{Yi Fei\} and Han, \{Xiao Long\} and Fan, \{Xiao Yang\} and Jun Tian and Gao, \{Yu Kun\} and You, \{Ting Ting\} and Yin, \{Peng Gang\}",

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year = "2024",

month = dec,

day = "27",

doi = "10.1021/acsapm.4c02670",

language = "英语",

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pages = "15124--15135",

journal = "ACS Applied Polymer Materials",

issn = "2637-6105",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - Polyrotaxane-Based Solid Polymer Electrolyte with a Macromolecular Crosslinker

AU - Wang, Rui Dong

AU - Zhang, Yi Fei

AU - Han, Xiao Long

AU - Fan, Xiao Yang

AU - Tian, Jun

AU - Gao, Yu Kun

AU - You, Ting Ting

AU - Yin, Peng Gang

PY - 2024/12/27

Y1 - 2024/12/27

N2 - This study explores an approach to incorporating polyrotaxane into solid polymer electrolytes (SPEs) through crosslinking with poly(ethylene glycol) (PEG). By leveraging the unique properties of polyrotaxane and the flexibility of PEG, we have developed SPEs with enhanced ionic conductivity, mechanical strength, and thermal stability. Our results indicate that the SPE film, containing equal weights of hydroxypropyl polyrotaxane (HyPR) and PEG with a molecular weight of 10000 Da, exhibits high thermal resistance above 150 °C, impressive flexibility with an elongation at break exceeding 550%, and an ionic conductivity of 2.715 × 10-5 S cm-1 at 30 °C.

AB - This study explores an approach to incorporating polyrotaxane into solid polymer electrolytes (SPEs) through crosslinking with poly(ethylene glycol) (PEG). By leveraging the unique properties of polyrotaxane and the flexibility of PEG, we have developed SPEs with enhanced ionic conductivity, mechanical strength, and thermal stability. Our results indicate that the SPE film, containing equal weights of hydroxypropyl polyrotaxane (HyPR) and PEG with a molecular weight of 10000 Da, exhibits high thermal resistance above 150 °C, impressive flexibility with an elongation at break exceeding 550%, and an ionic conductivity of 2.715 × 10-5 S cm-1 at 30 °C.

KW - cross-linking

KW - high ionic conductivity

KW - polyrotaxane

KW - slide-ring

KW - solid polymer electrolyte

UR - https://www.scopus.com/pages/publications/85213436994

U2 - 10.1021/acsapm.4c02670

DO - 10.1021/acsapm.4c02670

M3 - 文章

AN - SCOPUS:85213436994

SN - 2637-6105

VL - 6

SP - 15124

EP - 15135

JO - ACS Applied Polymer Materials

JF - ACS Applied Polymer Materials

IS - 24

ER -

Polyrotaxane-Based Solid Polymer Electrolyte with a Macromolecular Crosslinker

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Keywords

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