Perspective on cycling stability of lithium-iron manganese phosphate for lithium-ion batteries

Kun Zhang; Zi Xuan Li; Xiu Li; Xi Yong Chen; Hong Qun Tang; Xin Hua Liu; Cai Yun Wang; Jian Min Ma

doi:10.1007/s12598-022-02107-w

Perspective on cycling stability of lithium-iron manganese phosphate for lithium-ion batteries

Kun Zhang
, Zi Xuan Li
, Xiu Li^*
, Xi Yong Chen^*
, Hong Qun Tang^*
, Xin Hua Liu^*
, Cai Yun Wang
, Jian Min Ma

^*Corresponding author for this work

School of Transportation Science and Engineering

Guangxi University
University of Electronic Science and Technology of China
University of Wollongong

Research output: Contribution to journal › Review article › peer-review

49 Scopus citations

Abstract

Lithium-iron manganese phosphates (LiFe_xMn_1−xPO₄, 0.1 < x < 0.9) have the merits of high safety and high working voltage. However, they also face the challenges of insufficient conductivity and poor cycling stability. Some progress has been achieved to solve these problems. Herein, we firstly summarized the influence of different electrolyte systems on the electrochemical performance of LiFe_xMn_1−xPO₄, and then discussed the effect of element doping, lastly studied the influences of conductive layer coating and morphology control on the cycling stability. Finally, the prospects and challenges of developing high-cycling LiFe_xMn_1−xPO₄ were proposed. Graphical abstract: [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	740-750
Number of pages	11
Journal	Rare Metals
Volume	42
Issue number	3
DOIs	https://doi.org/10.1007/s12598-022-02107-w
State	Published - Mar 2023

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Cathode
Coating
Controlled synthesis
Cycling stability
Doping
Electrolyte modification
Lithium iron manganese phosphate

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10.1007/s12598-022-02107-w

Cite this

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title = "Perspective on cycling stability of lithium-iron manganese phosphate for lithium-ion batteries",

abstract = "Lithium-iron manganese phosphates (LiFexMn1−xPO4, 0.1 < x < 0.9) have the merits of high safety and high working voltage. However, they also face the challenges of insufficient conductivity and poor cycling stability. Some progress has been achieved to solve these problems. Herein, we firstly summarized the influence of different electrolyte systems on the electrochemical performance of LiFexMn1−xPO4, and then discussed the effect of element doping, lastly studied the influences of conductive layer coating and morphology control on the cycling stability. Finally, the prospects and challenges of developing high-cycling LiFexMn1−xPO4 were proposed. Graphical abstract: [Figure not available: see fulltext.].",

keywords = "Cathode, Coating, Controlled synthesis, Cycling stability, Doping, Electrolyte modification, Lithium iron manganese phosphate",

author = "Kun Zhang and Li, \{Zi Xuan\} and Xiu Li and Chen, \{Xi Yong\} and Tang, \{Hong Qun\} and Liu, \{Xin Hua\} and Wang, \{Cai Yun\} and Ma, \{Jian Min\}",

note = "Publisher Copyright: {\textcopyright} 2022, Youke Publishing Co.,Ltd.",

year = "2023",

month = mar,

doi = "10.1007/s12598-022-02107-w",

language = "英语",

volume = "42",

pages = "740--750",

journal = "Rare Metals",

issn = "1001-0521",

publisher = "John Wiley and Sons Inc",

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TY - JOUR

T1 - Perspective on cycling stability of lithium-iron manganese phosphate for lithium-ion batteries

AU - Zhang, Kun

AU - Li, Zi Xuan

AU - Li, Xiu

AU - Chen, Xi Yong

AU - Tang, Hong Qun

AU - Liu, Xin Hua

AU - Wang, Cai Yun

AU - Ma, Jian Min

PY - 2023/3

Y1 - 2023/3

N2 - Lithium-iron manganese phosphates (LiFexMn1−xPO4, 0.1 < x < 0.9) have the merits of high safety and high working voltage. However, they also face the challenges of insufficient conductivity and poor cycling stability. Some progress has been achieved to solve these problems. Herein, we firstly summarized the influence of different electrolyte systems on the electrochemical performance of LiFexMn1−xPO4, and then discussed the effect of element doping, lastly studied the influences of conductive layer coating and morphology control on the cycling stability. Finally, the prospects and challenges of developing high-cycling LiFexMn1−xPO4 were proposed. Graphical abstract: [Figure not available: see fulltext.].

AB - Lithium-iron manganese phosphates (LiFexMn1−xPO4, 0.1 < x < 0.9) have the merits of high safety and high working voltage. However, they also face the challenges of insufficient conductivity and poor cycling stability. Some progress has been achieved to solve these problems. Herein, we firstly summarized the influence of different electrolyte systems on the electrochemical performance of LiFexMn1−xPO4, and then discussed the effect of element doping, lastly studied the influences of conductive layer coating and morphology control on the cycling stability. Finally, the prospects and challenges of developing high-cycling LiFexMn1−xPO4 were proposed. Graphical abstract: [Figure not available: see fulltext.].

KW - Cathode

KW - Coating

KW - Controlled synthesis

KW - Cycling stability

KW - Doping

KW - Electrolyte modification

KW - Lithium iron manganese phosphate

UR - https://www.scopus.com/pages/publications/85141441847

U2 - 10.1007/s12598-022-02107-w

DO - 10.1007/s12598-022-02107-w

M3 - 文献综述

AN - SCOPUS:85141441847

SN - 1001-0521

VL - 42

SP - 740

EP - 750

JO - Rare Metals

JF - Rare Metals

IS - 3

ER -

Perspective on cycling stability of lithium-iron manganese phosphate for lithium-ion batteries

Abstract

UN SDGs

Keywords

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